Effects of cu and k on co-precipitated femn/sio2 catalysts for fischer-tropsch synthesis
文献类型：期刊论文
| 作者 | Zhang Cheng-Hua; Yang Yong; Tao Zhi-Chao; Li Ting-Zhen; Wan Hai-Jun; Xiang Hong-Wei; Li Yong-Wang |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 22期号:11页码:1310-1316 |
| 关键词 | Fischer-tropsch synthesis Fe-mn catalyst Copper Potassium Hydrocarbon distribution |
| ISSN号 | 1000-6818 |
| 通讯作者 | Xiang hong-wei(hwxiang@sxicc.ac.cn) |
| 英文摘要 | The effects of copper and potassium on the activity and selectivity of coprecipitated fe-mn/sio, catalysts for fischer-tropsch (f-t) synthesis were studied in a slurry phase continuous stirred tank reactor. the reduction and adsorption behaviors of the catalysts were investigated using temperature programmed reduction/temperature programmed desorption (tpr/tpd) methods. it was found that copper improves the reduction of the catalyst in h, or co. potassium improves the reduction of the catalyst in co, whereas it suppresses the reduction of the catalyst in h, copper enhances the h, adsorption, whereas potassium has no influence on the h-2 adsorption. in the f-t synthesis reaction, copper shortens the induction period required for reaching the steady state activity, whereas potassium prolongs the induction period. the potassium promoter increases the activity and decreases the selectivity of methane. the promotion effects of cu and k on the activity and selectivity is more obvious than that of cu, that is, the activity is higher and the methane selectivity is lower on the doubly promoted catalyst. |
| WOS关键词 | IRON-MANGANESE CATALYST ; SELECTIVITY ; FE ; ADSORPTION ; PROMOTER ; DIFFUSE ; CARBON |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000242290000002 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379306 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xiang Hong-Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Beijing 100864, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Cheng-Hua,Yang Yong,Tao Zhi-Chao,et al. Effects of cu and k on co-precipitated femn/sio2 catalysts for fischer-tropsch synthesis[J]. Acta physico-chimica sinica,2006,22(11):1310-1316. |
| APA | Zhang Cheng-Hua.,Yang Yong.,Tao Zhi-Chao.,Li Ting-Zhen.,Wan Hai-Jun.,...&Li Yong-Wang.(2006).Effects of cu and k on co-precipitated femn/sio2 catalysts for fischer-tropsch synthesis.Acta physico-chimica sinica,22(11),1310-1316. |
| MLA | Zhang Cheng-Hua,et al."Effects of cu and k on co-precipitated femn/sio2 catalysts for fischer-tropsch synthesis".Acta physico-chimica sinica 22.11(2006):1310-1316. |
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来源：中国科学院大学
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