Laser photolysis study of anthraquinone in binary mixtures of ionic liquid [bmim][pf6] and organic solvent
文献类型：期刊论文
| 作者 | Zhu, Guanglai; Xu, Jingjing; Wu, Guozhong; Zhu, Hongping; Long, Dewu; Chen, Shimou; Yao, Side |
| 刊名 | International journal of molecular sciences
 |
| 出版日期 | 2006-12-01 |
| 卷号 | 7期号:12页码:590-600 |
| 关键词 | 1-butyl-3-methylimidazolium hexafluorophosphate Laser photolysis Anthraquinone Rate constant |
| ISSN号 | 1422-0067 |
| 通讯作者 | Wu, guozhong(wuguozhong@sinap.ac.cn) |
| 英文摘要 | Photochemical properties of the ionic liquid (rtil) 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][pf6] and its binary mixed solutions with organic solvent (dmf and mecn) were investigated by laser photolysis at an excitation wavelength of 355 nm, using anthraquinone (aq) as a probe molecule. it was indicated that the triplet excited state of aq ((3)aq*) can abstract hydrogen from [bmim][pf6]. moreover, along with the change of the ratio of rtil and organic solvent, the reaction rate constant changes regularly. critical points were observed at volume fraction v-rtil=0.2 for rtil/mecn and v-rtil=0.05 for rtil/dmf. for both systems, before the critical point, the rate constant increases rapidly with increasing v-rtil; however, it decreases obviously with v-rtil after the critical point. we conclude that the concentration dependence is dominant at lower v-rtil, while the viscosity and phase transformation are dominant at higher v-rtil for the effect of ionic liquid on the decay of rate constant. |
| WOS关键词 | ROOM-TEMPERATURE ; METHYLTRIBUTYLAMMONIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE ; AQUEOUS-SOLUTION ; HEXAFLUOROPHOSPHATE ; 9,10-ANTHRAQUINONE ; PHOTOREDUCTION ; STATE ; REACTIVITY ; CATALYSIS ; ELECTRON |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000243883300003 |
| 出版者 | MDPI AG |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379309 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Guozhong |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China 2.Anhui Normal Univ, Inst Atom & Mol Phys, Wuhu 241000, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Guanglai,Xu, Jingjing,Wu, Guozhong,et al. Laser photolysis study of anthraquinone in binary mixtures of ionic liquid [bmim][pf6] and organic solvent[J]. International journal of molecular sciences,2006,7(12):590-600. |
| APA | Zhu, Guanglai.,Xu, Jingjing.,Wu, Guozhong.,Zhu, Hongping.,Long, Dewu.,...&Yao, Side.(2006).Laser photolysis study of anthraquinone in binary mixtures of ionic liquid [bmim][pf6] and organic solvent.International journal of molecular sciences,7(12),590-600. |
| MLA | Zhu, Guanglai,et al."Laser photolysis study of anthraquinone in binary mixtures of ionic liquid [bmim][pf6] and organic solvent".International journal of molecular sciences 7.12(2006):590-600. |
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来源：中国科学院大学
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