Evidence of the formation and conversion of unstable thionyl isocyanate: gas-phase spectroscopic studies
文献类型：期刊论文
| 作者 | Wang, Weigang; Yao, Li; Zeng, Xiaoqing; Ge, Maofa; Sun, Zheng; Wang, Dianxun; Ding, Yihong |
| 刊名 | Journal of chemical physics
 |
| 出版日期 | 2006-12-21 |
| 卷号 | 125期号:23页码:6 |
| ISSN号 | 0021-9606 |
| DOI | 10.1063/1.2403136 |
| 通讯作者 | Ge, maofa(gemaofa@iccas.ac.cn) |
| 英文摘要 | Thionyl diisocyanate which is unstable at ambient temperature is generated from a heterogeneous reaction of gaseous thionyl dichloride with silver cyanate and studied for the first time in the gas phase at 298 k. n-isocyanatoformyl sulfinylimide is also observed with photoelectron spectroscopy in the gas phase for the first time. the conversion of thionyl diisocyanate to n-isocyanatoformyl sulfinylimide via 1,3 shift at different temperatures is studied by using photoelectron spectroscopy and mass spectroscopy with the help of theoretical computations. on the basis of combined observations and quantum chemical calculations, possible 1,3-isocyanato shifts and dissociation processes for thionyl isocyanate and its cation have been discussed in detail. (c) 2006 american institute of physics. |
| WOS关键词 | 1ST EXPERIMENTAL-OBSERVATION ; PHOTOELECTRON-SPECTRA ; CARBONYL ISOCYANATES ; ELECTRON-DIFFRACTION ; MOLECULAR-PROPERTIES ; ACETYL ISOCYANATE ; REARRANGEMENT ; SULFUR |
| WOS研究方向 | Physics |
| WOS类目 | Physics, Atomic, Molecular & Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000243415300017 |
| 出版者 | AMER INST PHYSICS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379347 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Ge, Maofa |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Jilin Univ, Inst Theoret Chem, Changchun 130023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Weigang,Yao, Li,Zeng, Xiaoqing,et al. Evidence of the formation and conversion of unstable thionyl isocyanate: gas-phase spectroscopic studies[J]. Journal of chemical physics,2006,125(23):6. |
| APA | Wang, Weigang.,Yao, Li.,Zeng, Xiaoqing.,Ge, Maofa.,Sun, Zheng.,...&Ding, Yihong.(2006).Evidence of the formation and conversion of unstable thionyl isocyanate: gas-phase spectroscopic studies.Journal of chemical physics,125(23),6. |
| MLA | Wang, Weigang,et al."Evidence of the formation and conversion of unstable thionyl isocyanate: gas-phase spectroscopic studies".Journal of chemical physics 125.23(2006):6. |
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来源：中国科学院大学
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