Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions
文献类型:期刊论文
作者 | Sun, Shengling; Wang, Li; Wang, Aiqin |
刊名 | Journal of hazardous materials
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出版日期 | 2006-08-25 |
卷号 | 136期号:3页码:930-937 |
关键词 | Adsorption N,o-carboxymethyl-chitosan Crosslinked Lead Template |
ISSN号 | 0304-3894 |
DOI | 10.1016/j.jazmat.2006.01.033 |
通讯作者 | Wang, aiqin(aqwang@lzb.ac.cn) |
英文摘要 | In the current study, we attempt to find a new adsorbent material based on chitosan to improve adsorption selectivity for heavy metals, so that the crosslinked no-carboxymethyl-chitosan resin with pb(ii) as template ions (crosslinked cmc template) were synthesized by using cmc adsorbed pb(h) ions crosslinked with glutaraldehyde. the effects on adsorption capacities such as amount of crosslinking agent, degree of substitution of cmc, ph value of the initial solution and adsorption time were investigated. the adsorption experiments demonstrated the crosslinked cmc template has high adsorption selectivity for pb(ii) ions in solution containing single metal ions or coexistence of three metals ions of cu(ii), zn(ii) and pb(h). furthermore, it was investigated that the crosslinked cmc template has a good reusability and stability as compared to cnic. finally, we studied the adsorption mechanism by ftir spectra and xps analysis. the results reveal that the adsorption of crosslinked cmc template and cmc for pb(ii) is a chelation process. (c) 2006 elsevier b.v. all rights reserved. |
WOS关键词 | REMOVAL ; WATER ; METAL ; EQUILIBRIUM |
WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
WOS类目 | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
语种 | 英语 |
WOS记录号 | WOS:000240209700070 |
出版者 | ELSEVIER SCIENCE BV |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379368 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Aiqin |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Shengling,Wang, Li,Wang, Aiqin. Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions[J]. Journal of hazardous materials,2006,136(3):930-937. |
APA | Sun, Shengling,Wang, Li,&Wang, Aiqin.(2006).Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions.Journal of hazardous materials,136(3),930-937. |
MLA | Sun, Shengling,et al."Adsorption properties of crosslinked carboxymethyl-chitosan resin with pb(ii) as template ions".Journal of hazardous materials 136.3(2006):930-937. |
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来源:中国科学院大学
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