Photochemical rearomatization and dearomatization of tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes
文献类型：期刊论文
| 作者 | Zhou, L; Wu, LZ; Zhang, LP; Tung, CH |
| 刊名 | Organometallics
 |
| 出版日期 | 2006-03-27 |
| 卷号 | 25期号:7页码:1707-1711 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om050953b |
| 通讯作者 | Wu, lz(chtung@mail.ipc.ac.cn) |
| 英文摘要 | Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. in the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. the photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes. |
| WOS关键词 | 3-CENTER MN...H...C INTERACTION ; MANGANESE TRICARBONYL CATIONS ; DOUBLE NUCLEOPHILIC-ADDITION ; H BOND ACTIVATION ; CYCLOHEXENYLMANGANESE TRICARBONYL ; ELECTROPHILIC REACTIVITY ; ARENE ; 2-ELECTRON ; DICARBONYLNITROSYL(CYCLOHEXADIENYL)MANGANESE ; SUBSTITUENTS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000236288100022 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379411 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, LZ |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, L,Wu, LZ,Zhang, LP,et al. Photochemical rearomatization and dearomatization of tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes[J]. Organometallics,2006,25(7):1707-1711. |
| APA | Zhou, L,Wu, LZ,Zhang, LP,&Tung, CH.(2006).Photochemical rearomatization and dearomatization of tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes.Organometallics,25(7),1707-1711. |
| MLA | Zhou, L,et al."Photochemical rearomatization and dearomatization of tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes".Organometallics 25.7(2006):1707-1711. |
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来源：中国科学院大学
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