Grafting acrylic acid onto pre-irradiated polypropylene by reactive extrusion
文献类型：期刊论文
| 作者 | Cai Chuan-Lun; Xin Zhi-Rong; Yao Zhan-Hai; Shi Qiang; Yin Jing-Hua |
| 刊名 | Chemical journal of chinese universities-chinese
 |
| 出版日期 | 2006-10-01 |
| 卷号 | 27期号:10页码:1969-1973 |
| 关键词 | Polypropylene Reactive extrusion Electron beam pre-irradiation Acrylic acid |
| ISSN号 | 0251-0790 |
| 通讯作者 | Yin jing-hua(yinjh@ciac.jl.cn) |
| 英文摘要 | Polypropylene functionalized with acrylic acid(pp-g-aa) was prepared by coupling electron beam (eb) pre-irradiatian treatment with reactive extrusion process. the grafting samples were characterized by chemical titration, ftir, polarized light microphotographs, dsc and waxd. the study showed that grafting degree(gd) increased with increasing irradiation dose and then leveled off; the gd increased linearly with the aa concentration rising. it was observed that crystallization temperature of the grafted sample increased and crystallite size decreased, which can be attributed to the heterogeneous nucleating action of grafting chain. the mfr and mechanical properties measurements proved that serious. degradation of pp occured in the stage of pre-irradiation and extruding process. meanwhile, a mechanism of grafting reactions was proposed tentatively. |
| WOS关键词 | ISOTACTIC POLYPROPYLENE ; MALEIC-ANHYDRIDE ; MELT ; COPOLYMERIZATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000241440400044 |
| 出版者 | HIGHER EDUCATION PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379427 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yin Jing-Hua |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Yantai Univ, Coll Biol & Chem, Yantai 264005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai Chuan-Lun,Xin Zhi-Rong,Yao Zhan-Hai,et al. Grafting acrylic acid onto pre-irradiated polypropylene by reactive extrusion[J]. Chemical journal of chinese universities-chinese,2006,27(10):1969-1973. |
| APA | Cai Chuan-Lun,Xin Zhi-Rong,Yao Zhan-Hai,Shi Qiang,&Yin Jing-Hua.(2006).Grafting acrylic acid onto pre-irradiated polypropylene by reactive extrusion.Chemical journal of chinese universities-chinese,27(10),1969-1973. |
| MLA | Cai Chuan-Lun,et al."Grafting acrylic acid onto pre-irradiated polypropylene by reactive extrusion".Chemical journal of chinese universities-chinese 27.10(2006):1969-1973. |
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来源：中国科学院大学
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