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Investigations on the structural and magnetic properties of doubly substituted nd2fe17-x-ytixgay compounds (0 <= x <= 1.0, 0 <= y <= 3)

文献类型:期刊论文

作者Liu, XF; Chen, DF; Hao, YM; Lv, JY; Han, SB; Xue, YJ; Li, JH; Hu, ZB
刊名Journal of alloys and compounds
出版日期2006-01-05
卷号407期号:1-2页码:58-64
关键词Rare earth compounds Crystal structure X-ray diffraction Neutron diffraction Magnetic measurements
ISSN号0925-8388
DOI10.1016/j.jallcom.2005.06.042
通讯作者Hu, zb(huzq@gscas.ac.cn)
英文摘要The structural and magnetic properties of doubly substituted nd2fe17-x-ytixgay (0 <= x <= 1.0, 0 <= y <= 3) compounds have been investigated by a combined technique of x-ray diffraction, neutron diffraction and magnetic measurements. rietveld refinements of the diffraction data indicate that all the samples crystallize in the rhombohedral th2zn17-type structure. for a given ti content (x), the lattice parameters a, c, and unit cell volume v of nd2fe17-x-ytixgay. all increase linearly with increasing ga content. the addition of ti initially has a considerably positive effect on the increasing rates of a, c, and unit cell volume v, but later the effect becomes very slight and even negative with the further increase of ti content. the site occupancies of ti and ga in the crystallographic sites change a little compared to what is observed in the corresponding singly substituted compounds. the effects of ti and ga on the bond lengths of the doubly substituted compounds are quite different from that of the singly substituted compounds. magnetic measurements show the t-c of nd2fe17-x-ytixgay increases with increasing ti content for a low ga content while it behaves conversely for a higher ga content. the t-c of nd2fe17-x-ytixgay increases with increasing ga content for a particular ti content, while the addition of ti results in a slower increase of t-c on the ga content (y <= 3). for a given ti content, the m-s of nd2fe17-x-ytixgay first increases a little and then decreases with the increase of ga content, while for a given ga content the m-s of nd2fe17-x-ytixgay decreases with the increase of ti content. (c) 2005 elsevier b.v all rights reserved.
WOS关键词NEUTRON-DIFFRACTION ; SOLID-SOLUTIONS ; NB ; GA ; SI ; CR ; TI
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000234613600009
出版者ELSEVIER SCIENCE SA
URI标识http://www.irgrid.ac.cn/handle/1471x/2379464
专题中国科学院大学
通讯作者Hu, ZB
作者单位1.Chinese Acad Sci, Coll Chem & Chem Engn, Grad Sch, Beijing 100049, Peoples R China
2.China Inst Atom Energy, Beijing 102413, Peoples R China
推荐引用方式
GB/T 7714
Liu, XF,Chen, DF,Hao, YM,et al. Investigations on the structural and magnetic properties of doubly substituted nd2fe17-x-ytixgay compounds (0 <= x <= 1.0, 0 <= y <= 3)[J]. Journal of alloys and compounds,2006,407(1-2):58-64.
APA Liu, XF.,Chen, DF.,Hao, YM.,Lv, JY.,Han, SB.,...&Hu, ZB.(2006).Investigations on the structural and magnetic properties of doubly substituted nd2fe17-x-ytixgay compounds (0 <= x <= 1.0, 0 <= y <= 3).Journal of alloys and compounds,407(1-2),58-64.
MLA Liu, XF,et al."Investigations on the structural and magnetic properties of doubly substituted nd2fe17-x-ytixgay compounds (0 <= x <= 1.0, 0 <= y <= 3)".Journal of alloys and compounds 407.1-2(2006):58-64.

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