Synthesis and characterization of porphyrin-ferrocene-fullerene triads
文献类型：期刊论文
| 作者 | Li, YJ; Gan, ZH; Wang, N; He, XR; Li, YL; Wang, S; Liu, HB; Araki, Y; Ito, O; Zhu, DB |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2006-05-01 |
| 卷号 | 62期号:18页码:4285-4293 |
| 关键词 | Porphyrin Ferrocene Fullerene Conformation |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2006.02.076 |
| 通讯作者 | Li, yl(ylli@iccas.ac.cn) |
| 英文摘要 | Novel porphyrin-fullerene systems linked by ferrocene and related model compounds were successfully synthesized and characterized. conforniationally flexible 1,1'-disubstituted ferrocene functioned as effective modulator of the conformation between porphyrin and fullerene, as h-1 nmr spectra indicated, the porphyrin and c-60 moieties in the triads showed gauche type conformation. the electrochemical and photophysical studies showed that there were considerable interactions between porphyrin and fullerene in the ground state due to intramolecular pi-stacking of the these two chromophores, assisted by the ferrocence linker. fluorescence lifetime measurements indicated there might be two different quenching processes occurring simultaneously (intersystem crossing and electron transfer). (c) 2006 elsevier ltd. all rights reserved. |
| WOS关键词 | PHOTOINDUCED ELECTRON-TRANSFER ; CHARGE-TRANSFER INTERACTIONS ; ARTIFICIAL PHOTOSYNTHESIS ; INVERTED REGION ; SYSTEMS ; DYADS ; CHEMISTRY ; ELECTROCHEMISTRY ; RECOMBINATION ; DERIVATIVES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000237126200001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379466 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, YL |
| 作者单位 | 1.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan 2.Chinese Acad Sci, Grad Sch, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YJ,Gan, ZH,Wang, N,et al. Synthesis and characterization of porphyrin-ferrocene-fullerene triads[J]. Tetrahedron,2006,62(18):4285-4293. |
| APA | Li, YJ.,Gan, ZH.,Wang, N.,He, XR.,Li, YL.,...&Zhu, DB.(2006).Synthesis and characterization of porphyrin-ferrocene-fullerene triads.Tetrahedron,62(18),4285-4293. |
| MLA | Li, YJ,et al."Synthesis and characterization of porphyrin-ferrocene-fullerene triads".Tetrahedron 62.18(2006):4285-4293. |
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来源：中国科学院大学
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