Mechanism of synthesis of 1,5-naphthalene dicarbamate from 1,5-naphthalene diamine and dimethyl carbonate
文献类型：期刊论文
| 作者 | Xiao Fukui; Zhang Desheng; Dong Qingnian; Wen Dongmei; Pan Ling; Jiao Liping; Wei Wei; Sun Yuhan |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2006-07-01 |
| 卷号 | 27期号:7页码:573-578 |
| 关键词 | 1,5-naphthalene dicarbamate Zinc acetate 1,5-naphthalene diamine Dimethyl carbonate Reaction mechanism |
| ISSN号 | 0253-9837 |
| 通讯作者 | Xiao fukui() |
| 英文摘要 | The methoxycarbonylation mechanism of 1,5-naphthalene diamine with dimethyl carbonate catalyzed by zinc acetate was investigated by fourier transform infrared spectroscopy. zinc acetate dihydrate was not active for the reaction until it changed into anhydrous zinc acetate by losing the crystal water. anhydrous zinc acetate activated 1,5-naphthatene diamine by the formation of a new zinc complex. the new complex was a suitable nucleophilic reagent that could react with dimethyl carbonate to produce a methoxycarbonylation compound. when the complex of anhydrous zinc acetate with 1,5-naphthalene diamine was formed, the anhydrous zinc acetate changed from a bidentate ligand to a unidentate ligand. |
| WOS关键词 | AROMATIC DIAMINES ; ZINC ACETATE ; METHOXYCARBONYLATION ; CHEMISTRY |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000239715600010 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379486 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xiao Fukui |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Res Inst Jilin Petrochem Co Petrochina, Jilin 132021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao Fukui,Zhang Desheng,Dong Qingnian,et al. Mechanism of synthesis of 1,5-naphthalene dicarbamate from 1,5-naphthalene diamine and dimethyl carbonate[J]. Chinese journal of catalysis,2006,27(7):573-578. |
| APA | Xiao Fukui.,Zhang Desheng.,Dong Qingnian.,Wen Dongmei.,Pan Ling.,...&Sun Yuhan.(2006).Mechanism of synthesis of 1,5-naphthalene dicarbamate from 1,5-naphthalene diamine and dimethyl carbonate.Chinese journal of catalysis,27(7),573-578. |
| MLA | Xiao Fukui,et al."Mechanism of synthesis of 1,5-naphthalene dicarbamate from 1,5-naphthalene diamine and dimethyl carbonate".Chinese journal of catalysis 27.7(2006):573-578. |
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来源：中国科学院大学
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