中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and charaterization of ru complex with terpyridine on quartz substrates surface

文献类型:期刊论文

作者Zhao Jian-Ying; Ma Li; Jin Ri-Zhe; Gao Lian-Xun
刊名Chemical journal of chinese universities-chinese
出版日期2006-12-10
卷号27期号:12页码:2337-2339
关键词Self-assemble Pyridine Ru complex Schiff base
ISSN号0251-0790
通讯作者Gao lian-xun(lxgao@ciac.jl.cn)
英文摘要The 6-carboxaldehyde-2, 2': 6', 2"-terpyridine was synthesized and assembled on the aminosilanization quartz substrate by the schiff base interfacial group. then the substrate was reacted with ruthenium and 6-bromo-2,2'-bipyridine to form a new schiff base type ru complexes. the process of the complexes assembled was characterized by uv-vis absorption spectra and xps. the film exhibited photoluminescence arising from pi* -t(2g) ligand-to-metal transition of ru complex. from the fluorescent spectra, we observed the behavior of ru (ii) complexes is greatly affected by the schiff base ligand. the novel schiff base ligand ru (ii) complexes exhibited strong and pure luminescent intensity. it was different from the other type ruthenium complexes. the result shows that there are many ralations between the structure and the properties of the complex.
WOS关键词LUMINESCENCE ; CHEMILUMINESCENCE ; BINDING ; SILICA ; ACIDS
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000242962700023
出版者HIGHER EDUCATION PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2379598
专题中国科学院大学
通讯作者Gao Lian-Xun
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Zhao Jian-Ying,Ma Li,Jin Ri-Zhe,et al. Synthesis and charaterization of ru complex with terpyridine on quartz substrates surface[J]. Chemical journal of chinese universities-chinese,2006,27(12):2337-2339.
APA Zhao Jian-Ying,Ma Li,Jin Ri-Zhe,&Gao Lian-Xun.(2006).Synthesis and charaterization of ru complex with terpyridine on quartz substrates surface.Chemical journal of chinese universities-chinese,27(12),2337-2339.
MLA Zhao Jian-Ying,et al."Synthesis and charaterization of ru complex with terpyridine on quartz substrates surface".Chemical journal of chinese universities-chinese 27.12(2006):2337-2339.

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来源:中国科学院大学

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