Crystalline vanadium pentoxide with hierarchical mesopores and its capacitive behavior
文献类型：期刊论文
| 作者 | Liu, Hongtao; He, Ping; Li, Zhiying; Sun, Danzi; Huang, Haiping; Li, Jinghong; Zhu, Guoyi |
| 刊名 | Chemistry-an asian journal
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 1期号:5页码:701-706 |
| 关键词 | Capacitance Ionic liquids Mesoporous materials Template synthesis Vanadium |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.200600169 |
| 通讯作者 | Zhu, guoyi(zhuguoyi@ciac.jl.cn) |
| 英文摘要 | Crystalline vanadium pentoxide with hierarchical mesopores was synthesized by using a ctab/bmic cotemplate (ctab=cetyltrimethylammonium bromide, bmic=1-butyl-3-methylimidazolium chloride). the material was fully characterized by sem, tem, n(2) adsorption-desorption, xrd, xps, and cv methods. by elaborate adjustment of the template proportions, the distribution and size of the hierarchical pores were tuned successfully. ctab cationic surfactant contributed more to the larger mesopores, whereas bmic ionic liquid was beneficial in forming the smaller nanopores. the vanadium-containing anions combined with cta(+) micelles and bmi(+) rings through electrostatic interactions. the cta(+)-o(vo)o(-)-bmi(+) entities built up an orderly array, which finally formed the hierarchical mesoporous framework during thermal treatment. the mesoporous vanadium pentoxide directed by the cotemplate of ctab/ bmic=1:1 showed many orderly crystalline structures and demonstrated a large capacitance (225 fg(-1)); it is thus a promising material for electrochemical capacitors. two alternative solutions to the disappearance of capacitance due to insertion of k(+) are proposed in view of possible future applications. |
| WOS关键词 | TEMPERATURE IONIC LIQUIDS ; THIN-FILMS ; ELECTROCHEMICAL PROPERTIES ; NANOCASTING TECHNIQUE ; SOLVENT-EXTRACTION ; MOLECULAR-SIEVES ; METAL-IONS ; TEMPLATE ; SILICA ; OXIDE |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000243223200008 |
| 出版者 | WILEY-BLACKWELL |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379669 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhu, Guoyi |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.SW Univ Sci & Technol, Coll Mat Sci & Engn, Mianyang 621010, Peoples R China 4.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hongtao,He, Ping,Li, Zhiying,et al. Crystalline vanadium pentoxide with hierarchical mesopores and its capacitive behavior[J]. Chemistry-an asian journal,2006,1(5):701-706. |
| APA | Liu, Hongtao.,He, Ping.,Li, Zhiying.,Sun, Danzi.,Huang, Haiping.,...&Zhu, Guoyi.(2006).Crystalline vanadium pentoxide with hierarchical mesopores and its capacitive behavior.Chemistry-an asian journal,1(5),701-706. |
| MLA | Liu, Hongtao,et al."Crystalline vanadium pentoxide with hierarchical mesopores and its capacitive behavior".Chemistry-an asian journal 1.5(2006):701-706. |
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来源：中国科学院大学
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