Synthesis and crystal structure of [ca(dmf)(6)][mo6br8cl6]
文献类型：期刊论文
| 作者 | Liu, X; Cai, LZ; Guo, GC; Li, Q; Huang, JS |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 25期号:1页码:90-94 |
| 关键词 | Cluster Hydrogen bond Molybdenum Structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | Guo, gc() |
| 英文摘要 | The reaction of mobr2 with cacl2 in dmf (n, n'-dimethylformarnide) gives the cluster complex [ca(dmf)(6)][mo6br8cl6] 1 by using standard schlenk techniques. this cluster complex crystallizes in triclinic, space group p (1) over bar with a = 10.329(4), b = 10.349(4), c = 12.510(5) angstrom, alpha = 103.793(5), beta = 98.562(3), gamma = 98.268(5)degrees, v = 1261.5(9) angstrom(3), d-c = 2.509 g/cm(3), z = 1, c18h42br8cacl6mo6n6o6, m-r = 1906.28, mu = 8.236 mm(-1), lambda(mok alpha) = 0.71073 angstrom and f(000) = 894. the final r = 0.0589 and wr = 0.1458 for 2759 observed reflections with i > 2 sigma(1). the structure is composed of isolated octahedral coordination cations and discrete cluster anions, and these two kinds of ions connect each other to form a 3-d framework with similar packing patterns as cscl through weak c-(hx)-x-... (x = br, cl) hydrogen bonds. |
| WOS关键词 | NORMAL-COORDINATE ANALYSIS ; CLUSTER ANIONS ; VIBRATIONAL-SPECTRA ; SPECTROSCOPIC PROPERTIES ; COMPLEXES ; BR ; CL ; POLYMER ; HALIDES |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000234870400017 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379702 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Guo, GC |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, X,Cai, LZ,Guo, GC,et al. Synthesis and crystal structure of [ca(dmf)(6)][mo6br8cl6][J]. Chinese journal of structural chemistry,2006,25(1):90-94. |
| APA | Liu, X,Cai, LZ,Guo, GC,Li, Q,&Huang, JS.(2006).Synthesis and crystal structure of [ca(dmf)(6)][mo6br8cl6].Chinese journal of structural chemistry,25(1),90-94. |
| MLA | Liu, X,et al."Synthesis and crystal structure of [ca(dmf)(6)][mo6br8cl6]".Chinese journal of structural chemistry 25.1(2006):90-94. |
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来源：中国科学院大学
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