Hydrothermal synthesis and crystal structure of a square grid coordination copper(ii) polymer from 1,4-bis(imidazole-1-ylmethyl)benzene
文献类型：期刊论文
| 作者 | Li, T; Hu, SM; Li, ZH; Du, SW |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 25期号:1页码:85-89 |
| 关键词 | Hydrothermal method Copper(ii) Square grid Crystal structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | Du, sw() |
| 英文摘要 | The title compound [cu(bix)(2)(no3)(2)center dot h2o](n) 1 (bix =1,4-bis(imidazole-1-ylme-thyl) benzene) has been synthesized by hydrothermal method. its crystal structure is of monoclinic, space group p (1) over bar with a = 8.3075(13), b = 9.4725(13), c = 10.0192(13) angstrom, alpha = 91.088(4), beta = 104.063(6), gamma = 101.88(1), v= 746.5(3) angstrom(3), z = 1, c28h30n10o7cu1, m-r= 682.16, d-c = 1.518 g/cm(3), mu = 0.796 mm(-1), f(000) = 353, the final r = 0.0535 and wr = 0.0996 for 2921 observed reflections with i > 20(1). each bix ligand binds two cu(ii) ions to form a 2-d(4,4) square grid layer, which is connected by hydrogen bonds showing large channels occupied by solvated water molecules and nitrate anions. |
| WOS关键词 | SOLID-STATE ; 1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE ; NETWORK ; BIX ; BR |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000234870400016 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379704 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Du, SW |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, T,Hu, SM,Li, ZH,et al. Hydrothermal synthesis and crystal structure of a square grid coordination copper(ii) polymer from 1,4-bis(imidazole-1-ylmethyl)benzene[J]. Chinese journal of structural chemistry,2006,25(1):85-89. |
| APA | Li, T,Hu, SM,Li, ZH,&Du, SW.(2006).Hydrothermal synthesis and crystal structure of a square grid coordination copper(ii) polymer from 1,4-bis(imidazole-1-ylmethyl)benzene.Chinese journal of structural chemistry,25(1),85-89. |
| MLA | Li, T,et al."Hydrothermal synthesis and crystal structure of a square grid coordination copper(ii) polymer from 1,4-bis(imidazole-1-ylmethyl)benzene".Chinese journal of structural chemistry 25.1(2006):85-89. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。