Electrochemical behavior and multilayer films of the sandwich-type polyoxotungstate complex {k10co4(h2o)(2)(pw9o34)(2)}
文献类型：期刊论文
| 作者 | Gao, Shuiying; Li, Taohai; Li, Xing; Cao, Rong |
| 刊名 | Materials letters
 |
| 出版日期 | 2006-12-01 |
| 卷号 | 60期号:29-30页码:3622-3626 |
| 关键词 | Sandwich polyoxometalate Electrochemistry Cyclic voltammetry Multilayer film |
| ISSN号 | 0167-577X |
| DOI | 10.1016/j.matlet.2006.03.104 |
| 通讯作者 | Cao, rong(rcao@ms.fjirsm.ac.cn) |
| 英文摘要 | The electrochemical behavior of the sandwich-type polyoxotungstate complex of k10co4(h2o)(2)(pw9o34)(2) (co-4(pw9)(2)) was investigated by cyclic voltammetry in aqueous solutions. the polyoxoanion exhibits two successive redox peaks originating from the tungsten-oxo framework. the electrochemical behavior for the co-ii species was not detected. moreover, the multilayer films consisting of pei and co-4(pw9)(2) were prepared by the layer-by-layer self-assembly method. the films were characterized by uv-vis spectroscopy, cyclic voltammetry and. atomic force image. the films exhibit the electrochemical behavior of co-4(pw9)(2) polyoxoanion. moreover, the films can catalyze the electrochemical reduction) of no2-. electron transfer to fe(cn)(6)(3-/4-) redox probe was also investigated. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | DAWSON-TYPE POLYOXOMETALATE ; AQUEOUS-SOLUTION ; NITRIC-OXIDE ; HETEROPOLYANIONS ; REDUCTION ; HETEROPOLYTUNGSTATES ; CATALYSIS ; OXIDATION ; ANIONS ; NMR |
| WOS研究方向 | Materials Science ; Physics |
| WOS类目 | Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| WOS记录号 | WOS:000242469000043 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379734 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, Rong |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Shuiying,Li, Taohai,Li, Xing,et al. Electrochemical behavior and multilayer films of the sandwich-type polyoxotungstate complex {k10co4(h2o)(2)(pw9o34)(2)}[J]. Materials letters,2006,60(29-30):3622-3626. |
| APA | Gao, Shuiying,Li, Taohai,Li, Xing,&Cao, Rong.(2006).Electrochemical behavior and multilayer films of the sandwich-type polyoxotungstate complex {k10co4(h2o)(2)(pw9o34)(2)}.Materials letters,60(29-30),3622-3626. |
| MLA | Gao, Shuiying,et al."Electrochemical behavior and multilayer films of the sandwich-type polyoxotungstate complex {k10co4(h2o)(2)(pw9o34)(2)}".Materials letters 60.29-30(2006):3622-3626. |
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来源：中国科学院大学
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