Preparation of polyethylene-graft-polymethacrylates and polyethylene-graft-poly(acrylic aced) via reactive monomer method
文献类型：期刊论文
| 作者 | Li Huayi; Zhang Xiaofan; Chen Shangtao; Lu Yingying; Ke Yucai; Hu Youliang |
| 刊名 | Acta polymerica sinica
 |
| 出版日期 | 2006-10-01 |
| 期号 | 7页码:848-854 |
| 关键词 | Polyethylene Functionalization Reactive monomer P-allyltoluene Graft copolymer |
| ISSN号 | 1000-3304 |
| 通讯作者 | Li huayi() |
| 英文摘要 | Ethylene and p-allyltoluene were copolymerized in the presence of metallocene catalyst rac-ethylenebis(indenyl) zirconium dichloride-mao. the polyethylene ( pe) copolymer prepared was brominated using radical initiator and n-bromosuccininiide. h-1-nmr showed that each benzyl site was substituted with one bromine atom. methyl mathacrylate and t-butyl acrylate were polymerized via atrp process with brominated pe copolymer as macromolecular initiator and cucl/n, n, n', n', n"-pentamethyldiethylenetriarnine as catalyst and the corresponding graft copolymer was synthesized. polyethylene-graft-poly( t-butyl acrylate) was subsequently converted by hydrolysis with hydrochloric acid to polyethylene-graft-poly(crylic acid), which was father converted to polyethylene-graft-poly( sodium acrylate) by reacting with sodium hydroxide. mulao test indicated that the polarity of polyethylene graft copolymers relative to that of polyethylene was improved greatly. |
| WOS关键词 | TRANSFER RADICAL POLYMERIZATION ; POLYOLEFIN COPOLYMERS ; BLOCK-COPOLYMERS ; BUTYL ACRYLATE ; FUNCTIONALIZATION ; POLYPROPYLENE ; METALLOCENE ; POLYSTYRENE ; CATALYSTS |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000241636600002 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379766 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li Huayi |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Huayi,Zhang Xiaofan,Chen Shangtao,et al. Preparation of polyethylene-graft-polymethacrylates and polyethylene-graft-poly(acrylic aced) via reactive monomer method[J]. Acta polymerica sinica,2006(7):848-854. |
| APA | Li Huayi,Zhang Xiaofan,Chen Shangtao,Lu Yingying,Ke Yucai,&Hu Youliang.(2006).Preparation of polyethylene-graft-polymethacrylates and polyethylene-graft-poly(acrylic aced) via reactive monomer method.Acta polymerica sinica(7),848-854. |
| MLA | Li Huayi,et al."Preparation of polyethylene-graft-polymethacrylates and polyethylene-graft-poly(acrylic aced) via reactive monomer method".Acta polymerica sinica .7(2006):848-854. |
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来源：中国科学院大学
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