Synthesis of amphiphilic ethyl cellulose grafting poly(acrylic acid) copolymers and their self-assembly morphologies in water
文献类型：期刊论文
| 作者 | Kang, Hongliang; Liu, Wenyong; He, Benqiao; Shen, Dawa; Ma, Lin; Huang, Yong |
| 刊名 | Polymer
 |
| 出版日期 | 2006-10-30 |
| 卷号 | 47期号:23页码:7927-7934 |
| 关键词 | Ethyl cellulose-g-poly(acrylic acid) Atrp Self-assembly |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2006.09.017 |
| 通讯作者 | Huang, yong(yhuang@cashq.ac.cn) |
| 英文摘要 | Amphiphilic ethyl cellulose (ec)-g-poly(acrylic acid) (paa) copolymers were synthesized by atom transfer radical polymerization (atrp). firstly, ethyl cellulose macro-initiators with the degree of the 2-bromoisobutyryl substitution of 0.04 and 0.25 synthesized by the esterification of the hydroxyl groups remained in ec macromolecular chains and the 2-bromoisobutyryl bromides. secondly, tert-butyl acrylate was polymerized by atrp with the ethyl cellulose macro-initiator and ec-g-ptba copolymers were prepared. finally, the ec-g-paa copolymers were prepared by hydrolyzing tert-butyl group of the ec-g-ptba copolymers. the grafting copolymers were characterized by means of gpc, h-1 nmr and ftir spectroscopies. the molecular weight of graft copolymers increased during the polymerization and the polydispersity was low. a kinetic study showed that the polymerization was first-order. meanwhile, ec-g-paa copolymers were self-assembled to micelles or particles with diameters of 5 nm and 100 nm in water (ph = 10) when the concentration was 1.0 mg/ml. (c) 2006 elsevier ltd. all rights reserved. |
| WOS关键词 | TRANSFER RADICAL POLYMERIZATION ; ABC TRIBLOCK COPOLYMERS ; TERT-BUTYL ACRYLATE ; BLOCK-COPOLYMERS ; METHYL-METHACRYLATE ; MOLECULAR BRUSHES ; STAR POLYMERS ; STYRENE ; ATRP ; NANOPARTICLES |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000242416700010 |
| 出版者 | ELSEVIER SCI LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379782 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Huang, Yong |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem,BNLMS, Beijing 100080, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Chem, Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Hongliang,Liu, Wenyong,He, Benqiao,et al. Synthesis of amphiphilic ethyl cellulose grafting poly(acrylic acid) copolymers and their self-assembly morphologies in water[J]. Polymer,2006,47(23):7927-7934. |
| APA | Kang, Hongliang,Liu, Wenyong,He, Benqiao,Shen, Dawa,Ma, Lin,&Huang, Yong.(2006).Synthesis of amphiphilic ethyl cellulose grafting poly(acrylic acid) copolymers and their self-assembly morphologies in water.Polymer,47(23),7927-7934. |
| MLA | Kang, Hongliang,et al."Synthesis of amphiphilic ethyl cellulose grafting poly(acrylic acid) copolymers and their self-assembly morphologies in water".Polymer 47.23(2006):7927-7934. |
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来源：中国科学院大学
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