One new schiff base complex with one in situ synthesized ligand: synthesis and structure
文献类型：期刊论文
| 作者 | Li Ya-Min; Zhang Jian-Jun; Sheng Tian-Lu; Fu Rui-Biao; Hu Sheng-Min; Lai Zhu-Zhi; Wu Xin-Tao |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2006 |
| 卷号 | 25期号:8页码:891-894 |
| 关键词 | Schiff base Guanidinate Single-crystal structure |
| ISSN号 | 0254-5861 |
| 通讯作者 | Wu xin-tao(wxt@ms.fjirsm.ac.cn) |
| 英文摘要 | One new ni(ii) complex [ni(h2l)]cl(h2o)(3) based on one in-situ synthesized schiff base ligand h3l (h3l = bis(benzyl-2-pyridylidene)-diaminoguanidine) was prepared and structurally characterized by single-crystal x-ray diffraction method. the complex crystallizes in the monoclinic system, space group c2/c with a = 27.944(7), b = 7.7405(19), c = 25.999(7) angstrom, beta = 115.545(2)degrees, v = 5074(2) angstrom(3), m-r = 566.69, z = 8, d-c = 1.484 g/cm(3), f(000) = 2352, mu(mok alpha) = 0.912 nm(-1), r = 0.0594 and wr = 0.1477 for 5145 observed reflections (i > 2 sigma(i)). the complex exhibits one mononuclear structure in which the ni(ii) atom adopts a [nin4] pseudo-planar square geometry. interestingly, along the b axis, each two neighboring [ni(h2l)](+) units by an inverse center form pairs of molecules through the intermolecular benzene-pyridine pi(...)pi interactions. |
| WOS关键词 | CATALYSIS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000240156700001 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379860 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu Xin-Tao |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Ya-Min,Zhang Jian-Jun,Sheng Tian-Lu,et al. One new schiff base complex with one in situ synthesized ligand: synthesis and structure[J]. Chinese journal of structural chemistry,2006,25(8):891-894. |
| APA | Li Ya-Min.,Zhang Jian-Jun.,Sheng Tian-Lu.,Fu Rui-Biao.,Hu Sheng-Min.,...&Wu Xin-Tao.(2006).One new schiff base complex with one in situ synthesized ligand: synthesis and structure.Chinese journal of structural chemistry,25(8),891-894. |
| MLA | Li Ya-Min,et al."One new schiff base complex with one in situ synthesized ligand: synthesis and structure".Chinese journal of structural chemistry 25.8(2006):891-894. |
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来源：中国科学院大学
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