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Different molecular frameworks of zinc(ii) and cadmium(ii) coordination polymers constructed by flexible double betaine ligands

文献类型:期刊论文

作者Wu, AQ; Li, Y; Zheng, FK; Guo, GC; Huang, JS
刊名Crystal growth & design
出版日期2006-02-01
卷号6期号:2页码:444-450
ISSN号1528-7483
DOI10.1021/cg050378e
通讯作者Zheng, fk()
英文摘要A series of six novel zn(cd)-double betaine coordination polymers have been obtained by the mild reactions of the respective metal nitrate with three flexible double betaine ligands. single-crystal x-ray structural analyses reveal that the six complexes possess different molecular frameworks derived from various coordination modes and flexibilities of double betaine ligands, which indicates that the nature of the ligands has a great influence on the structural topologies of the metal-organic molecular architectures. extensive hydrogen bonds play important roles in crystal packing and supramolecular frameworks. it is noteworthy that the different one-dimensional water chains with "arm-chair" and "zigzag" characteristics are presented in the complexes zn(l-2)(h2o)(no3)]no3)center dot 2h(2)o (3) and [cd(l-2)(h2o)(no3)]no(3)center dot 3h(2)o (4) [l-2 = 1,3-bis(pyridinio-4-acetato)-propane], respectively.
WOS关键词DICARBOXYLATE-LIKE LIGANDS ; NONLINEAR-OPTICAL MATERIALS ; CRYSTAL-STRUCTURES ; STRUCTURAL-CHARACTERIZATION ; ORGANIC FRAMEWORK ; COMPLEXES ; NETWORKS ; ARCHITECTURES ; WATER ; BIS(4-PYRIDYL)
WOS研究方向Chemistry ; Crystallography ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Crystallography ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000235228600017
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2379910
专题中国科学院大学
通讯作者Zheng, FK
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wu, AQ,Li, Y,Zheng, FK,et al. Different molecular frameworks of zinc(ii) and cadmium(ii) coordination polymers constructed by flexible double betaine ligands[J]. Crystal growth & design,2006,6(2):444-450.
APA Wu, AQ,Li, Y,Zheng, FK,Guo, GC,&Huang, JS.(2006).Different molecular frameworks of zinc(ii) and cadmium(ii) coordination polymers constructed by flexible double betaine ligands.Crystal growth & design,6(2),444-450.
MLA Wu, AQ,et al."Different molecular frameworks of zinc(ii) and cadmium(ii) coordination polymers constructed by flexible double betaine ligands".Crystal growth & design 6.2(2006):444-450.

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来源:中国科学院大学

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