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Study on superabsorbent composite - vii. effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite

文献类型:期刊论文

作者Zhang, Jun Ping; Chen, Hao; Wang, Ai Qin
刊名Polymers for advanced technologies
出版日期2006-05-01
卷号17期号:5页码:379-385
关键词Superabsorbent Composites Organification Swelling Networks
ISSN号1042-7147
DOI10.1002/pat.722
通讯作者Wang, ai qin(aqwang@lzb.ac.cn)
英文摘要A novel multifunctional superabsorbent composite from acrylic acid (aa), acrylamide (am), sodium humate (sh) and organo-attapulgite (organo-apt), paa-am/sh/organo-apt, was synthesized by aqueous solution polymerization, using n,n'-methylenebisacrylamide (mba) as a crosslinker and ammonium persulfate (aps) as an initiator. the organification of apt with hexadecyltrimethyl ammonium bromide (hdtmabr) was proved by ft-ir. the effects of organo-apt (hdtma-apt) content in the superabsorbent composite and organification degree of it on water absorbency of the superabsorbent composite were studied. the effects of incorporated hdtma-apt on swelling rate, water absorbency in various saline solutions and reswelling capability of the superabsorbent composite were also investigated. the results indicate that organification of apt had a remarkable influence on swelling behaviors of the superabsorbent composites. comparing with the composite doped with apt, water absorbency for the composite incorporated with 10 wt% hdtma-apt was enhanced from 996 to 1282 g g(-1) in distilled water and from 63 to 68 g g(-1) in 0.9 wt% nacl solution, respectively. the superabsorbent composite acquired its highest water absorbency when the organification degree of apt was 8.02wt%. water absorbency of the composites in various saline solutions decreased with the increasing concentration, especially for the multivalent cations. in addition, swelling rate and reswelling capability of the superabsorbent composite were also improved by introducing hdtma-apt into the composite compared with that of incorporating apt. copyright (c) 2006 john wiley & sons, ltd.
WOS关键词2-ACRYLAMIDO-2-METHYLPROPANESULFONIC ACID ; GRAFT-POLYMERIZATION ; STARCH ; HYDROGELS ; POLYMERS ; PH ; NANOCOMPOSITE ; ACRYLATE
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000239044900007
出版者JOHN WILEY & SONS LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2379934
专题中国科学院大学
通讯作者Wang, Ai Qin
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecol & Green Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Zhang, Jun Ping,Chen, Hao,Wang, Ai Qin. Study on superabsorbent composite - vii. effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite[J]. Polymers for advanced technologies,2006,17(5):379-385.
APA Zhang, Jun Ping,Chen, Hao,&Wang, Ai Qin.(2006).Study on superabsorbent composite - vii. effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite.Polymers for advanced technologies,17(5),379-385.
MLA Zhang, Jun Ping,et al."Study on superabsorbent composite - vii. effects of organification of attapulgite on swelling behaviors of poly(acrylic acid-co-acrylamide)/sodium humate/organo-attapulgite composite".Polymers for advanced technologies 17.5(2006):379-385.

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来源:中国科学院大学

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