C-80 encaging four different atoms: the synthesis, isolation, and characterizations of scyern@c-80
文献类型：期刊论文
| 作者 | Chen, Ning; Zhang, Er-Yun; Wang, Chun-Ru |
| 刊名 | Journal of physical chemistry b
 |
| 出版日期 | 2006-07-13 |
| 卷号 | 110期号:27页码:13322-13325 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp062982l |
| 通讯作者 | Wang, chun-ru(crwang@iccas.ac.cn) |
| 英文摘要 | The synthesis, isolation, and spectroscopic characterizations of an endohedral fullerene with four heteroatoms encapsulated (scyern@c-80) are reported for the first time. the isomeric structure and electronic properties of this molecule are studied by various spectrometry methods such as high-performance liquid chromatography (hplc), laser desorption time-of-flight (ld-tof) mass spectroscopy, cyclic voltammetry, fourier transform infrared (ftir) spectroscopy, and visible-near infrared (vis-nir) absorption spectroscopy. the carbon cage of scyern@c-80 is assigned as i-h-c-80, and the four-membered scyern cluster is suggested to rotate rapidly inside the fullerene cage. six electrons are transferred from the nuclear cluster scyern to the fullerene cage, which leads to a closed-shell electronic structure of the i-h-c-80 and results in excellent stability of this molecule. |
| WOS关键词 | FIELD-EFFECT TRANSISTOR ; ENDOHEDRAL METALLOFULLERENES ; CRYSTALLOGRAPHIC CHARACTERIZATION ; ELECTRONIC-STRUCTURE ; CONTRAST AGENTS ; FULLERENES ; SC3N-AT-C-80 ; LA-2-AT-C-80 ; PR-AT-C-82 ; LA-AT-C-82 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000238806000005 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379960 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Chun-Ru |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Ning,Zhang, Er-Yun,Wang, Chun-Ru. C-80 encaging four different atoms: the synthesis, isolation, and characterizations of scyern@c-80[J]. Journal of physical chemistry b,2006,110(27):13322-13325. |
| APA | Chen, Ning,Zhang, Er-Yun,&Wang, Chun-Ru.(2006).C-80 encaging four different atoms: the synthesis, isolation, and characterizations of scyern@c-80.Journal of physical chemistry b,110(27),13322-13325. |
| MLA | Chen, Ning,et al."C-80 encaging four different atoms: the synthesis, isolation, and characterizations of scyern@c-80".Journal of physical chemistry b 110.27(2006):13322-13325. |
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来源：中国科学院大学
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