V-cu composite oxide catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate
文献类型：期刊论文
| 作者 | Tong Dongshen; Chen Tong; Yao Jie; Wang Yue; Wang Gongying; Shi Dachuan; Li Zheng; Chen Zhiming |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 28期号:3页码:190-192 |
| 关键词 | Vanadium Copper Composite oxide Dimethyl carbonate Phenol Transesterification Diphenyl carbonate |
| ISSN号 | 0253-9837 |
| 通讯作者 | Tong dongshen() |
| 英文摘要 | The v-cu composite oxide catalyst was prepared by coprecipitation and used for the synthesis of diphenyl carbonate (dpc) by transesterification of dimethyl carbonate (dmc) with phenol. the effect of the molar ratio of v/cu and the reusability of the catalyst were investigated. the catalyst showed the highest activity with a v/cu molar ratio of 4/1. under the conditions of 150 similar to 180 degrees c and 9 h, the conversion of phenol and the transesterification selectivity over the v-cu catalyst were 37.0 % and 96.8 %, respectively. according to the x-ray diffraction results, the v-cu composite oxide was composed of crystalline v2o5 and cuv2o6 at v/cu = 4/1. both crystalline v2o5 and cuv2o6 were the active phase. in addition, the activity of the catalyst was reduced from 37.0 % to 23.7 % after the catalyst was reused three times. however, the used catalyst could be easily regenerated by calcination at 550 degrees c in air for 5 h, and the catalytic activity of the regenerated catalyst was almost as high as that of the fresh sample. |
| WOS关键词 | REACTIVITY |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000245616800002 |
| 出版者 | SCIENCE CHINA PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2379989 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Tong Dongshen |
| 作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.CNPC, Jilin Petrochem Co, Jilin 132021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong Dongshen,Chen Tong,Yao Jie,et al. V-cu composite oxide catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate[J]. Chinese journal of catalysis,2007,28(3):190-192. |
| APA | Tong Dongshen.,Chen Tong.,Yao Jie.,Wang Yue.,Wang Gongying.,...&Chen Zhiming.(2007).V-cu composite oxide catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate.Chinese journal of catalysis,28(3),190-192. |
| MLA | Tong Dongshen,et al."V-cu composite oxide catalyst for transesterification of dimethyl carbonate with phenol to diphenyl carbonate".Chinese journal of catalysis 28.3(2007):190-192. |
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来源：中国科学院大学
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