Molecular modeling of poly(p-phenylenevinylene): synthesis and photophysical properties of oligomers
文献类型：期刊论文
| 作者 | Jiu, Tonggang; Li, Yuliang; Liu, Xiaofeng; Liu, Huibiao; Li, Cuihong; Ye, Jianping; Zhu, Daoben |
| 刊名 | Journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 45期号:5页码:911-924 |
| 关键词 | Fluorescence Linear Oligomers Photophysical properties Static quenching |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.21862 |
| 通讯作者 | Li, yuliang(ylli@iccas.ac.cn) |
| 英文摘要 | A series of oligo(phenylenevinylene)s (opvs) of different lengths containing aldehyde and dialdehyde groups on the ends were synthesized and characterized. their photophysical properties were also investigated via ultraviolet-visible, steady-state, and time-resolved fluorescence spectra. the results indicated that the absorption maximum, radiative rate constant, and excitation maximum of an opvncho oligomer series (where n represents the oligomeric length) showed linear relationships with the reciprocal number of conjugated units. similarly, the absorption maximum and emission lifetime of the oligomers of an opvn-2cho series showed linear relationships with the reciprocal number of conjugated units. the dependence of the fluorescence intensities of the opvs on the concentration of the quencher c-60 was evaluated. apparently, upon photoexcitation, the opvs underwent significant fluorescence quenching. the results for different opv derivatives and a quenching mechanistic discussion showed that the static quenching contribution was indeed responsible for the significant upward curvature. (c) 2007 wiley periodicals, inc. |
| WOS关键词 | PHOTOINDUCED ELECTRON-TRANSFER ; PHENYLENE VINYLENE OLIGOMERS ; CHARGE-TRANSFER ; ALKOXY SUBSTITUTION ; CONJUGATED POLYMERS ; OPTICAL-ABSORPTION ; CHAIN-LENGTH ; DERIVATIVES ; TRANSISTOR ; SPECTRA |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000244267700019 |
| 出版者 | JOHN WILEY & SONS INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380020 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Li, Yuliang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiu, Tonggang,Li, Yuliang,Liu, Xiaofeng,et al. Molecular modeling of poly(p-phenylenevinylene): synthesis and photophysical properties of oligomers[J]. Journal of polymer science part a-polymer chemistry,2007,45(5):911-924. |
| APA | Jiu, Tonggang.,Li, Yuliang.,Liu, Xiaofeng.,Liu, Huibiao.,Li, Cuihong.,...&Zhu, Daoben.(2007).Molecular modeling of poly(p-phenylenevinylene): synthesis and photophysical properties of oligomers.Journal of polymer science part a-polymer chemistry,45(5),911-924. |
| MLA | Jiu, Tonggang,et al."Molecular modeling of poly(p-phenylenevinylene): synthesis and photophysical properties of oligomers".Journal of polymer science part a-polymer chemistry 45.5(2007):911-924. |
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来源：中国科学院大学
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