Recent examples of divergent catalysis in organic reactions: unexpected findings or rational design?
文献类型：期刊论文
| 作者 | Xu, Li-Wen; Li, Li; Lai, Guo-Qiao |
| 刊名 | Mini-reviews in organic chemistry
 |
| 出版日期 | 2007-08-01 |
| 卷号 | 4期号:3页码:217-230 |
| 关键词 | Divergent catalysis Homogeneous catalysis Organic reaction Carbon-carbon bond Carbon-heteroatom bond |
| ISSN号 | 1570-193X |
| 通讯作者 | Xu, li-wen(licpxulw@yahoo.com) |
| 英文摘要 | The term 'divergent catalysis' describes different catalytic chemical reactions that occur with the same substrates (reactants) under controllable conditions, especially using different catalysts. various substrates were found to work with versatile reactivity under different catalytic conditions, resulting in the formation of different products. however, the examples of rationally designed divergent catalysis are still few. this review is focused on the achievements of divergent catalysis with the simplest substrates in the past decades. it includes divergent catalysis of one-component and two-component reactions with the same and simple reagents, ranging from carbon-carbon-forming pinacol coupling, benzoin condensation, ullmann coupling, c-h homocoupling or activation, ring-closing metathesis, cyclization, stetter reaction, baylis-hillman reaction, friedel-crafts reaction, c-h heck coupling, 1,2-additon reaction and michael addition, to the carbon-heteroatom bond-forming c-n cross coupling, hydroamination reaction, aza-michael reaction, c-h oxidative amination, acetalization, and esterification. |
| WOS关键词 | CROSS-COUPLING REACTIONS ; ENYNE CYCLOISOMERIZATION REACTION ; BAYLIS-HILLMAN REACTIONS ; AZA-MICHAEL REACTION ; C BOND FORMATION ; CARBONYL-COMPOUNDS ; BENZOIN CONDENSATION ; OLEFIN METATHESIS ; ENANTIOSELECTIVE ADDITION ; PROPARGYLIC ALCOHOLS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000249869300003 |
| 出版者 | BENTHAM SCIENCE PUBL LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380200 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Li-Wen |
| 作者单位 | 1.Hangzhou Normal Univ, Minist Educ, State Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Grad Sch, State Key Lab Oxo Synt & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Li-Wen,Li, Li,Lai, Guo-Qiao. Recent examples of divergent catalysis in organic reactions: unexpected findings or rational design?[J]. Mini-reviews in organic chemistry,2007,4(3):217-230. |
| APA | Xu, Li-Wen,Li, Li,&Lai, Guo-Qiao.(2007).Recent examples of divergent catalysis in organic reactions: unexpected findings or rational design?.Mini-reviews in organic chemistry,4(3),217-230. |
| MLA | Xu, Li-Wen,et al."Recent examples of divergent catalysis in organic reactions: unexpected findings or rational design?".Mini-reviews in organic chemistry 4.3(2007):217-230. |
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来源：中国科学院大学
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