A novel approach for the preparation of pmma-pdms core-shell particles with pdms in the shell
文献类型：期刊论文
| 作者 | Deng, Xiaobo; Liu, Bailing; Cao, Shunsheng; Luo, Rong; Chen, Hualin |
| 刊名 | Applied surface science
 |
| 出版日期 | 2007-03-30 |
| 卷号 | 253期号:11页码:4823-4829 |
| 关键词 | Core/shell particles Pmma Mps Pdms |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2006.10.057 |
| 通讯作者 | Liu, bailing(blliuchem@hotmail.com) |
| 英文摘要 | The core/shell particles consisting of polymethyl methacrylate (pmma) core and polydimethylsiloxane (pdms) shell via 3-(methacryloxypropyl)-trimethoxysilane (mps) as the medium to link the core and shell were prepared in our present study by successive seeding polymerization under kinetically controlled conditions and were characterized by ft-jr, particle size analyzer, transmission electron microscopy (tem) and xray photoelectron spectroscopy (xps). the picture of optical microscope showed the clear form of pdms-0 and pdms-40 (the content of pdms in the particles), which approached to monodispersed distribution. compared with the pmma microspheres, pdms-40 presented an evident core/shell structure through the observation of tem. additionally, the study of xps revealed that pdms could be grafted onto the surface of pmma particles and the atomic ratio of c/si on the surface of pdms-40 was very close to the ratio of c/si in the molecule of pdms. the surface properties of the films produced from the core/ shell microspheres also were investigated by contact angle method, contrast with the homopolymer of pmma, the core/shell particles were more effective to form hydrophobic surface and the water repellency on the surface would be better than that of pmma. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | POLY(METHYL METHACRYLATE) ; CORE/SHELL PARTICLES ; BLOCK-COPOLYMERS ; LATEX-PARTICLES ; AMINO-SILANE ; SURFACE ; NANOPARTICLES ; COATINGS ; STYRENE |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| WOS类目 | Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000245500200002 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380216 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Liu, Bailing |
| 作者单位 | Chinese Acad Sci, Grad Sch, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Xiaobo,Liu, Bailing,Cao, Shunsheng,et al. A novel approach for the preparation of pmma-pdms core-shell particles with pdms in the shell[J]. Applied surface science,2007,253(11):4823-4829. |
| APA | Deng, Xiaobo,Liu, Bailing,Cao, Shunsheng,Luo, Rong,&Chen, Hualin.(2007).A novel approach for the preparation of pmma-pdms core-shell particles with pdms in the shell.Applied surface science,253(11),4823-4829. |
| MLA | Deng, Xiaobo,et al."A novel approach for the preparation of pmma-pdms core-shell particles with pdms in the shell".Applied surface science 253.11(2007):4823-4829. |
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来源：中国科学院大学
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