中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Photoinduced graft copolymerization of polymer surfactants based on hydroxyethyl cellulose

文献类型:期刊论文

作者Li, Zhengxing; Wang, Linge; Huang, Yong
刊名Journal of photochemistry and photobiology a-chemistry
出版日期2007-07-05
卷号190期号:1页码:9-14
关键词Polymer surfactant Hydroxyethyl cellulose Ultraviolet copolymerization
ISSN号1010-6030
DOI10.1016/j.jphotochem.2007.03.005
通讯作者Wang, linge(lg-wang@gic.ac.cn)
英文摘要A novel polymer surfactant, hydroxyethyl cellulose-based copolymer, was prepared via ultraviolet (uv) irradiation by copolymerizing hydroxyethyl cellulose (hec) with hexadecyl acrylate (hda) and comonomer styrene (st) in aqueous solution. the purified graft copolymer was characterized by ft-ir and h-1 nmr, which showed that hda and st were grafted on hec chains under uv irradiation. effects of uv irradiation time, ph value of the reaction solution and monomer volume percent in the feed on the chemical structure and the surface tension of graft copolymer were investigated. the result showed that the grafting of hda on the hec was limited by the grafting of st under uv irradiation, and the graft copolymer performed excellent surface activity when the grafting was under an appropriate conditions (i.e. both the volume percent of hda and st in the feed were 4% (v/v), the ph value of the reaction solution was 7 and the uv irradiation time was 1 h). (c) 2007 elsevier b.v. all rights reserved.
WOS关键词UV-IRRADIATION ; DERIVATIVE SURFACTANTS ; AQUEOUS-SOLUTIONS ; METHYL ; METHACRYLATE ; DEGRADATION ; PHOTOLYSIS ; TENSION ; SYSTEM
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
WOS记录号WOS:000247857900002
出版者ELSEVIER SCIENCE SA
URI标识http://www.irgrid.ac.cn/handle/1471x/2380232
专题中国科学院大学
通讯作者Wang, Linge
作者单位1.Chinese Acad Sci, Guangzhou Inst Chem, Key Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Li, Zhengxing,Wang, Linge,Huang, Yong. Photoinduced graft copolymerization of polymer surfactants based on hydroxyethyl cellulose[J]. Journal of photochemistry and photobiology a-chemistry,2007,190(1):9-14.
APA Li, Zhengxing,Wang, Linge,&Huang, Yong.(2007).Photoinduced graft copolymerization of polymer surfactants based on hydroxyethyl cellulose.Journal of photochemistry and photobiology a-chemistry,190(1),9-14.
MLA Li, Zhengxing,et al."Photoinduced graft copolymerization of polymer surfactants based on hydroxyethyl cellulose".Journal of photochemistry and photobiology a-chemistry 190.1(2007):9-14.

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来源:中国科学院大学

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