Effect of atmospheric interfering absorption on measurement of BTX by DOAS
文献类型：期刊论文
| 作者 | Peng, Fu-min1,2; Xie, Pin-hua1; Li, Hai-yang3; Zhang, Ying-hua1; Wang, Jun-de3; Liu, Wen-qing1 |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2008-06-01 |
| 卷号 | 21期号:3页码:202-210 |
| 关键词 | differential optical absorption spectroscopy BTX Herzberg band O-2 dimer |
| ISSN号 | 1674-0068 |
| 产权排序 | 3;3 |
| 通讯作者 | pin-hua xie |
| 英文摘要 | it was reported on the elimination of interfering absorption of btx. the absorption of o-2 includes different absorption bands, which change differently when the partial pressure of oxygen is varied. these cause the nonlinear absorption of o-2 and the observed band shape to vary with the column density of o-2 the absorption ratios of molecular absorption in each of the herzberg hands and dimer absorptions, as well as the contribution to the correction error of molecular absorption, are studied based on the characteristic of these absorption bands. the optimized way, to eliminate the interfering absorption is obtained in the end and the effectiveness of using interpolation proposed by volkamer et al. to remove o-2 absorption is proved again. as to o-3 and so2, the effect of the thermal effect of characteristic spectra on the elimination error of their absorption is studied. solutions to these problems are discussed and demonstrated together with methods to optimize the interpolation of spectra. as a sample application, differential optical absorption spectroscopy (doas) measurements of btx are carried out. results show a low detection limit and the good correlation with point instruments are achieved. all these prove the feasibility of using spectral interpolation to improve the accuracy of doas measurements of aromatic hydrocarbons for practical purposes. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | fourier-transform spectroscopy ; cross-section measurements ; herzberg-i bands ; aromatic-hydrocarbons ; urban air ; 295 k ; o-2 ; oxygen ; benzene ; toluene |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000258577500002 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101553]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Environm Opt & Technol, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China 2.Anhui Univ, Coll Chem & Chem Engn, Hefei 230039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Fu-min,Xie, Pin-hua,Li, Hai-yang,et al. Effect of atmospheric interfering absorption on measurement of BTX by DOAS[J]. chinese journal of chemical physics,2008,21(3):202-210. |
| APA | Peng, Fu-min,Xie, Pin-hua,Li, Hai-yang,Zhang, Ying-hua,Wang, Jun-de,&Liu, Wen-qing.(2008).Effect of atmospheric interfering absorption on measurement of BTX by DOAS.chinese journal of chemical physics,21(3),202-210. |
| MLA | Peng, Fu-min,et al."Effect of atmospheric interfering absorption on measurement of BTX by DOAS".chinese journal of chemical physics 21.3(2008):202-210. |
入库方式： OAI收割
来源：大连化学物理研究所
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