Vibrational spectroscopic investigation of light-induced polymerization process of epoxy resin, polytetrahydrofuran and spirobislactone
文献类型：期刊论文
| 作者 | Zhang, Yujie; Xu, Jingwei; Chen, Zhengjun; Qin, Chuangye; Dou, Yanli |
| 刊名 | Polymer international
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 56期号:7页码:914-918 |
| 关键词 | Epoxy resin Ftir Cationic polymerization Expanding monomer Anionic polymerization |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.2224 |
| 通讯作者 | Xu, jingwei(jwxu@ciac.ji.cn) |
| 英文摘要 | The light-induced polymerization process of bisphenol f diglycidyl. ether (bfdge), 5,5 ' dicarboxylic-7,7 '-dioxo-2,2 '-spirodi(benzotetrahydrofuran) (dcsibl) and polytetrahydrofuran (pthf-250) was studied. 4-[(2-hydroxytetradecyl)oxy]phenyl-phenyliodoniumhex.ifluoroantimonate, camphorquinone and ethyl 4-dimethylaminobenzoate were used as a photoinitiator system. the polymerization process was induced by light and monitored using fourier transform infrared spectroscopy. a novel combination-initiation polymerization process was proposed: first, cationic copolymerization of bfdge and pthf-250 was initiated by the photoinitiator system and heat was released by this polymerization; then, copolymerization of bfdge and dcsbl was induced by that heat while pthf-250 served as an anionic initiator. (c) 2007 society of chemical industry. |
| WOS关键词 | SPIROCYCLIC BIS(GAMMA-LACTONE)S ; CATIONIC COPOLYMERIZATION ; LANTHANUM TRIFLATE ; DENTAL COMPOSITES ; POLYMERS ; SHRINKAGE ; INITIATOR |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000247218700013 |
| 出版者 | JOHN WILEY & SONS LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380275 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu, Jingwei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Natl Analyt Res Ctr Electrochem & Spect, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Jilin Univ, Inst Mat Sci & Technol, Changchun 130025, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yujie,Xu, Jingwei,Chen, Zhengjun,et al. Vibrational spectroscopic investigation of light-induced polymerization process of epoxy resin, polytetrahydrofuran and spirobislactone[J]. Polymer international,2007,56(7):914-918. |
| APA | Zhang, Yujie,Xu, Jingwei,Chen, Zhengjun,Qin, Chuangye,&Dou, Yanli.(2007).Vibrational spectroscopic investigation of light-induced polymerization process of epoxy resin, polytetrahydrofuran and spirobislactone.Polymer international,56(7),914-918. |
| MLA | Zhang, Yujie,et al."Vibrational spectroscopic investigation of light-induced polymerization process of epoxy resin, polytetrahydrofuran and spirobislactone".Polymer international 56.7(2007):914-918. |
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来源：中国科学院大学
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