Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(iii) complexes: [ni(c3h10n2)(3)]sb4s7, [c4h14n2]sb8s13 center dot h2o, and [c6h18n2]sb10s16 center dot h2o
文献类型：期刊论文
| 作者 | Zhang, Meng; Sheng, Tian Lu; Huang, Xi He; Fu, Rui Biao; Wang, Xin; Hu, Sheng Min; Xiang, Sheng Chang; Wu, Xin Tao |
| 刊名 | European journal of inorganic chemistry
 |
| 出版日期 | 2007-04-01 |
| 期号 | 11页码:1606-1612 |
| 关键词 | Thioantimonates Solvothermal synthesis Cations Layered compounds |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200601030 |
| 通讯作者 | Wu, xin tao(wxt@fjirsm.ac.cn) |
| 英文摘要 | Three new thioantimonate(iii) complexes [ni(1,2-pda)(3)]-sb4s7 (1) (1,2-pda = 1,2-propanediamine), [dmenh(2)(2+)]-sb8s13 center dot h2o (2) (dmen = n,n-dimethylethylenediamine), and [deenh(2)(2+)] sb10s16 center dot h2o (3) (deen = n,n-diethylethylenediamine), prepared under solvothermal conditions, have been characterized by single-crystal x-ray diffraction, elemental analysis, and dta-tg measurements. in compound 1, a rectangle-like sb16s16 heteroring whose dimensions are about 8.1 x 14.7 angstrom is observed, this is the largest reported,pore in layered thioantimonates to date. further condensation of the sb16s16 heterorings resulted in an unprecedented framework of the five-atom thick sbxsyn- layer. in 2, a new member of sbnsn (n = 2, 3, 4, 8, 16, 30, 31, 32) heterocycles sb15s15 heteroring has been obtained as the first example. in compound 3, the most particular feature is that when the secondary sb-s bonds are considered the sb2 atom becomes sevenfold coordinated. (c) wiley-vch verlag gmbh & co. kgaa, 69451 weinheim, germany, 2007. |
| WOS关键词 | STRUCTURE-DIRECTING AGENTS ; HYDROTHERMAL SYNTHESIS ; LAYERED THIOANTIMONATE(III) ; ANTIMONY-SULFIDE ; METAL-COMPLEXES ; TRANSITION ; CHAIN ; LA ; COMPOUND ; LIGANDS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000246224400017 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380324 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Xin Tao |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Meng,Sheng, Tian Lu,Huang, Xi He,et al. Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(iii) complexes: [ni(c3h10n2)(3)]sb4s7, [c4h14n2]sb8s13 center dot h2o, and [c6h18n2]sb10s16 center dot h2o[J]. European journal of inorganic chemistry,2007(11):1606-1612. |
| APA | Zhang, Meng.,Sheng, Tian Lu.,Huang, Xi He.,Fu, Rui Biao.,Wang, Xin.,...&Wu, Xin Tao.(2007).Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(iii) complexes: [ni(c3h10n2)(3)]sb4s7, [c4h14n2]sb8s13 center dot h2o, and [c6h18n2]sb10s16 center dot h2o.European journal of inorganic chemistry(11),1606-1612. |
| MLA | Zhang, Meng,et al."Solvothermal synthesis, crystal structure, and thermal stability of three-layered thioantimonate(iii) complexes: [ni(c3h10n2)(3)]sb4s7, [c4h14n2]sb8s13 center dot h2o, and [c6h18n2]sb10s16 center dot h2o".European journal of inorganic chemistry .11(2007):1606-1612. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。