中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite

文献类型:期刊论文

作者Zhao Xueying; Chen Lidong; Bai Shengqiang; Pei Yanzhong; Li Xiaoya
刊名Rare metal materials and engineering
出版日期2007-08-01
卷号36页码:415-418
关键词Fe doping Filled skutterudite Thermoelectric
ISSN号1002-185X
通讯作者Zhao xueying(zhaoxy@mail.sic.ac.cn)
英文摘要Skutterudite compounds sr0.5co4-xfexsb12 were synthesized by melting method and the thermal and electrical properties were measured in the temperature range of 300 similar to 850 k. the results of x-ray diffraction (xrd) and electron microprobe analyses (epma) identified that all the samples contain sr0.5co4-xfexsb12 skutterudite as the main phase with a trace amount of fesb2 and cosb2 impurities. all samples exhibit p-type conduction. the carrier concentration and electrical conductivity of the samples increase with increasing iron content and the seebeck coefficient decreases. the lattice thermal conductivity of the samples decreased with the increase of iron content due to the vacancy point defect phonon scattering at co site introduced by iron. the lowest lattice thermal conductivity at room temperature is about 1.97 wrn(-1)k(-2). the highest zt value of 0.6 is obtained for sr0.52co2.32fe1.68sb12 compound at 850 k.
WOS关键词TRANSPORT-PROPERTIES ; FILLING FRACTION ; FE CONTENT ; BARIUM
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000250915200121
出版者NORTHWEST INST NONFERROUS METAL RESEARCH
URI标识http://www.irgrid.ac.cn/handle/1471x/2380412
专题中国科学院大学
通讯作者Zhao Xueying
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhao Xueying,Chen Lidong,Bai Shengqiang,et al. Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite[J]. Rare metal materials and engineering,2007,36:415-418.
APA Zhao Xueying,Chen Lidong,Bai Shengqiang,Pei Yanzhong,&Li Xiaoya.(2007).Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite.Rare metal materials and engineering,36,415-418.
MLA Zhao Xueying,et al."Synthesis and thermoelectric properties of p-type sr0.5co4-xfexsb12 skutterudite".Rare metal materials and engineering 36(2007):415-418.

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来源:中国科学院大学

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