Conformational isomerism of 1,2-bis(imidazol-1 '-yl)ethane in five-coordination polymers: influence of metal ions and m-isophthalate ligands bearing different substituents
文献类型：期刊论文
| 作者 | Li, Xiao-Ju; Cao, Rong; Guo, Zhen-Gang; Li, Ya-Feng; Zhu, Xian-Dong |
| 刊名 | Polyhedron
 |
| 出版日期 | 2007-08-31 |
| 卷号 | 26期号:14页码:3911-3919 |
| 关键词 | Conformational isomerisms Coordination polymers Solvothermal reaction X-ray diffraction |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2007.04.043 |
| 通讯作者 | Cao, rong(rcao@ms.fjirsm.ac.cn) |
| 英文摘要 | Four novel coordination polymers, {[zn(gauche-bime)(bdc)]center dot 0.5h(2)o}(n) (1), {[zn(anti-bime)(ho-bdc)]center dot 2.5h(2)o}(n) (2), [cu(gauche-bime)(0.5)(anti-bime)(0.5)(o2n-bdc)](n) (4) and [ni-2(gauche-bime)(anti-bime)(o2n-bdc)(2)(h2o)(2)](n) (5) were successfully prepared by the solvothermal reactions of 1,2-bis(imidazol-1'-yl)ethane (bime), m-isophthalic acid (h(2)bdc) or its two derivatives (ho-h(2)bdc = 5-hydroxyisophthalic acid, o2n-h(2)bdc = 5-nitroisophthalic acid) with different metal ions. interestingly, bime in the four complexes exhibit different conformations owing to the synergetic influence of coexistent neutral (-h), electron-donating (-oh) or electron-withdrawing (-no2,) groups of the dicarboxylate ligands and different metal ions. in 1 and 2, only one conformation of bime (gauche in i and anti in 2) is displayed, while the mixed conformations of bime (gauche:anti = 1: 1) are observed in 4 and 5. at the same time, one previously reported compound {[zn(anti-bime)(o2n-bdc)]center dot h2o}(n) (3) as a comparable substance in the research system was also mentioned, in which the anti-conformation of bime was observed. (c) 2007 elsevier ltd. all rights reserved. |
| WOS关键词 | COORDINATION POLYMER ; SUPRAMOLECULAR ISOMERISM ; 3-DIMENSIONAL NETWORK ; ORGANIC FRAMEWORKS ; MIXED-LIGANDS ; CO ; OCTAHEDRON ; TOPOLOGY ; BEHAVIOR ; RIBBONS |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000249714200048 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380439 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, Rong |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiao-Ju,Cao, Rong,Guo, Zhen-Gang,et al. Conformational isomerism of 1,2-bis(imidazol-1 '-yl)ethane in five-coordination polymers: influence of metal ions and m-isophthalate ligands bearing different substituents[J]. Polyhedron,2007,26(14):3911-3919. |
| APA | Li, Xiao-Ju,Cao, Rong,Guo, Zhen-Gang,Li, Ya-Feng,&Zhu, Xian-Dong.(2007).Conformational isomerism of 1,2-bis(imidazol-1 '-yl)ethane in five-coordination polymers: influence of metal ions and m-isophthalate ligands bearing different substituents.Polyhedron,26(14),3911-3919. |
| MLA | Li, Xiao-Ju,et al."Conformational isomerism of 1,2-bis(imidazol-1 '-yl)ethane in five-coordination polymers: influence of metal ions and m-isophthalate ligands bearing different substituents".Polyhedron 26.14(2007):3911-3919. |
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来源：中国科学院大学
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