A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex
文献类型：期刊论文
| 作者 | Wu, Ming-Yan; Yuan, Da-Qiang; Chen, Bai-Quan; Huang, You-Gui; Jiang, Feilong; Hong, Mao-Chun |
| 刊名 | Supramolecular chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 19期号:6页码:411-417 |
| 关键词 | P-sulfonatothiacalix[4] arene Copper Supramolecular capsule Crystal structure |
| ISSN号 | 1061-0278 |
| DOI | 10.1080/10610270601064736 |
| 通讯作者 | Hong, mao-chun(hmc@fjirsm.ac.cn) |
| 英文摘要 | The reaction of tetrasodium p-sulfonatothiacalix[4] arene ( na(4)h(4)tcas), copper( ii) nitrate and pyridine n- oxide ( pno) afforded a yellow copper( ii)-p-sulfonatothiacalix[ 4] arene complex. x-ray diffraction analysis displays that it is an interesting dimeric supramolecular capsule, [cu-2( pno)(2)( h2o)(6)](4+), [( h(6)tcas)(2)](4+)center dot 22h(2)o, in which two pno molecules bridge the two cu ii ions in the o,o'- mu(2) mode and the hydrophobic aromatic rings point into the cavities of the thiacalixarenes. interestingly, the thiacalixarenes pack themselves into the closed pores through pi center dot center dot center dot pi interactions in ab plane, and these pores further link to each other through hydrogen bonding to construct infinite hydrophilic tunnels, which fill with the disordered water molecules as the guests. |
| WOS关键词 | MOLECULAR CAPSULES ; METAL-COMPLEXES ; COORDINATION ; ENCAPSULATION ; CONFINEMENT ; SUPERANIONS ; CALIXARENE ; BILAYERS ; CATIONS ; SITES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000250011400008 |
| 出版者 | TAYLOR & FRANCIS LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380507 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Hong, Mao-Chun |
| 作者单位 | Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Ming-Yan,Yuan, Da-Qiang,Chen, Bai-Quan,et al. A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex[J]. Supramolecular chemistry,2007,19(6):411-417. |
| APA | Wu, Ming-Yan,Yuan, Da-Qiang,Chen, Bai-Quan,Huang, You-Gui,Jiang, Feilong,&Hong, Mao-Chun.(2007).A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex.Supramolecular chemistry,19(6),411-417. |
| MLA | Wu, Ming-Yan,et al."A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex".Supramolecular chemistry 19.6(2007):411-417. |
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来源：中国科学院大学
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