Synthesis and crystal structure of [k(18-crown-6)](3)p-11 center dot 2en
文献类型：期刊论文
| 作者 | Dai Feng-Rong; Xu Li |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 26期号:1页码:45-48 |
| 关键词 | Zintl ions Phosphorus Crystal structure Undecaphosphide |
| ISSN号 | 0254-5861 |
| 通讯作者 | Xu li(xli@fjirsm.ac.cn) |
| 英文摘要 | The undecaphosphide anion in ethylenediamine/18-crown-6 solution is isolated as [k(18-crown-6)](3)p-11 center dot 2en 1. the crystal structure has been determined by single-crystal x-ray diffraction. the crystal is of monoclinic, space group p2(1) with a = 13.4731(7), b = 16.1123(6), c = 16.5117(g) angstrom, beta = 112.133(2)degrees, v = 3320.3(3) angstrom(3), d-c = 1.371 g/cm(3) c40h88k3n4o18p11, m-r = 1371.11, f(000) 1444, mu = 0.532 mm(-1), z = 2, r = 0.0544 and wr = 0.1326 for 11423 observed reflections (i > 2 sigma(i)). the "naked" p-11(3-) ion is stabilized by two partly sequestered potassiums. the third partly sequestered potassium does not interact with the p atom (p(6)) but with two solvent molecules. |
| WOS关键词 | PRIMARY PHOSPHANE ; POLYPHOSPHIDES ; PHOSPHIDES ; CHEMISTRY ; ANIONS ; RB4P6 |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000243778200009 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380535 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xu Li |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai Feng-Rong,Xu Li. Synthesis and crystal structure of [k(18-crown-6)](3)p-11 center dot 2en[J]. Chinese journal of structural chemistry,2007,26(1):45-48. |
| APA | Dai Feng-Rong,&Xu Li.(2007).Synthesis and crystal structure of [k(18-crown-6)](3)p-11 center dot 2en.Chinese journal of structural chemistry,26(1),45-48. |
| MLA | Dai Feng-Rong,et al."Synthesis and crystal structure of [k(18-crown-6)](3)p-11 center dot 2en".Chinese journal of structural chemistry 26.1(2007):45-48. |
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来源：中国科学院大学
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