Synthesis and crystal structure of a new cesium barium borate, csbab3o6
文献类型：期刊论文
| 作者 | Chen, Guojun; Wu, Yicheng; Fua, Peizhen |
| 刊名 | Journal of solid state chemistry
 |
| 出版日期 | 2007-08-01 |
| 卷号 | 180期号:8页码:2194-2201 |
| 关键词 | Cesium barium borate Csbab3o6 Crystal structure Nonlinear optical (nlo) materials |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2007.05.014 |
| 通讯作者 | Wu, yicheng(ycwu@cl.cryo.ac.cn) |
| 英文摘要 | A new ternary borate oxide, cesium barium borate, csbab3o6, has been synthesized by solid-state reaction at 700 degrees c, and the single crystals were grown using csf as a flux. the crystal structure has been determined by x-ray diffraction. it crystallizes in the trigonal space group p321 with a cell of dimensions a = 12.469(3)angstrom, c = 7.444(3)angstrom, alpha = 90.00 degrees, gamma = 120.00 degrees, v = 1002.3(5)angstrom(3), z = 6. the fundamental building units of csbab3o6 are the b3o6 plane hexagonal rings, which are parallel to each other and stack along the c-axis, and the cs and ba atoms alternately occupy sites between the b3o6 sheets. a comparison of the structures of csbab3o6, beta-bab2o4 and csbo2 is presented. (c) 2007 elsevier inc. all rights reserved. |
| WOS关键词 | RELATIVE PROPERTIES ; MM'(4)(BO3)(3) M ; SR ; METABORATE ; OPTICS ; NA ; BA ; M' |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000249186100002 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380540 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Yicheng |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 10039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Guojun,Wu, Yicheng,Fua, Peizhen. Synthesis and crystal structure of a new cesium barium borate, csbab3o6[J]. Journal of solid state chemistry,2007,180(8):2194-2201. |
| APA | Chen, Guojun,Wu, Yicheng,&Fua, Peizhen.(2007).Synthesis and crystal structure of a new cesium barium borate, csbab3o6.Journal of solid state chemistry,180(8),2194-2201. |
| MLA | Chen, Guojun,et al."Synthesis and crystal structure of a new cesium barium borate, csbab3o6".Journal of solid state chemistry 180.8(2007):2194-2201. |
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来源：中国科学院大学
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