Preparation, composition and structures of reactive nonionic surfactants
文献类型：期刊论文
| 作者 | Li Li-Li; Cai Chuan-Lun; Xin Zhi-Rong; Shi Qiang; Yin Jin-Hua |
| 刊名 | Chemical journal of chinese universities-chinese
 |
| 出版日期 | 2007-04-10 |
| 卷号 | 28期号:4页码:779-782 |
| 关键词 | Nomonic surfactant Glycerol monostearate Glycerol monooleate Sorbitan monooleate Acrylic acid |
| ISSN号 | 0251-0790 |
| 通讯作者 | Yin jin-hua(yinjh@ciac.jl.cn) |
| 英文摘要 | Three reactive nonionic surfactants with 1-olefinic bond were synthesized. glycerol monostearate gms), glycerol monooleate( a300), and sorbitan monooleate( span 80) were adopted as the starting materials to react with acrylic acid( aa) separately, p-toluene sulfonic acid as the catalyst and hydroquinone as the inhibitor. the conversion of the products was determined by means of aa adding level and the amount of the residual aa in the system. it was shown that the conversion of aa got to about 91%, and the yields of three different products, agms, aa 300 and aspan 80 are over 80% respectively. spectra of mr, h-1 nmr and fticr-ms were used to further confirm the formation of the three target products and their chemical structures. then they were grafted with lldpe, the t-c of the grafted lldpe is higher than the plain, and the contact angles of the water on the grafted lldpe film decrease. the terms of antifogging were prolonged when the grafted lldpe was used as the agriculture films. |
| WOS关键词 | MALEIC-ANHYDRIDE ; EXTRUSION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000245874300043 |
| 出版者 | HIGHER EDUCATION PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2380731 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yin Jin-Hua |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Ploymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Li-Li,Cai Chuan-Lun,Xin Zhi-Rong,et al. Preparation, composition and structures of reactive nonionic surfactants[J]. Chemical journal of chinese universities-chinese,2007,28(4):779-782. |
| APA | Li Li-Li,Cai Chuan-Lun,Xin Zhi-Rong,Shi Qiang,&Yin Jin-Hua.(2007).Preparation, composition and structures of reactive nonionic surfactants.Chemical journal of chinese universities-chinese,28(4),779-782. |
| MLA | Li Li-Li,et al."Preparation, composition and structures of reactive nonionic surfactants".Chemical journal of chinese universities-chinese 28.4(2007):779-782. |
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来源：中国科学院大学
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