Oxo-anion binding by protonated (dimethylphenyl)(pyridyl) ureas
文献类型：期刊论文
| 作者 | Wu, Biao; Huang, Xiaojuan; Xia, Yazhao; Yang, Xiao-Juan; Janiak, Christoph |
| 刊名 | Crystengcomm
 |
| 出版日期 | 2007 |
| 卷号 | 9期号:8页码:676-685 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/b702278f |
| 通讯作者 | Wu, biao(wubiao@lzb.ac.cn) |
| 英文摘要 | The anion coordination chemistry of two protonated urea-based ligands, n-(2,4-dimethylphenyl)n'-(3-pyridy1) urea (1) and n-(2,6-dimethylphenyl)-n'-(3-pyridy1) urea (2) is reported. reaction of 1 or 2 with inorganic oxo-acids such as perchloric, nitric or sulfuric acid affords the adducts (3 -6) of the corresponding anions with protonated ligands (1h(+) and 2h(+)). the solid-state structures of the anion complexes display a rich variety of hydrogen bond motifs involving the urea nh groups, carbonyl, protonated pyridyl nh+ fragment, water molecules, and the anions. while complexes with ligand 1 (3 and 4) crystallize as monohydrate, compounds with 2 (5 and 6) are solvent-free, which leads to notable differences in their hydrogen bond patterns. when crystallized from the acid mixture hclo4/hno3 or hclo4/h2so4 both 1 and 2 selectively bind the perchlorate anion. |
| WOS关键词 | HYDROGEN-BOND ; PI-STACKING ; COMPLEXES ; RECEPTORS ; LIGANDS ; IONS ; CHLORIDE ; SYNTHON ; DIMENSIONALITY ; RECOGNITION |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Multidisciplinary ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000248352900019 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381152 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Biao |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou 730000, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 4.Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany 5.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Biao,Huang, Xiaojuan,Xia, Yazhao,et al. Oxo-anion binding by protonated (dimethylphenyl)(pyridyl) ureas[J]. Crystengcomm,2007,9(8):676-685. |
| APA | Wu, Biao,Huang, Xiaojuan,Xia, Yazhao,Yang, Xiao-Juan,&Janiak, Christoph.(2007).Oxo-anion binding by protonated (dimethylphenyl)(pyridyl) ureas.Crystengcomm,9(8),676-685. |
| MLA | Wu, Biao,et al."Oxo-anion binding by protonated (dimethylphenyl)(pyridyl) ureas".Crystengcomm 9.8(2007):676-685. |
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来源：中国科学院大学
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