Distinct m and p helical complexes of h2o and metal ions ni-ii, cu-ii, and zn-ii with enantiomerically pure chiral bis(pyrrol-2-ylmethyleneamine)cyclohexane ligands: crystal structures and circular dichroism properties
文献类型：期刊论文
| 作者 | Wang, Yaobing; Fu, Hongbing; Shen, Fugang; Sheng, Xiaohai; Peng, Aidong; Gu, Zhanjun; Ma, Hongwei; Ma, Jin Shi; Yao, Jiannian |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2007-04-30 |
| 卷号 | 46期号:9页码:3548-3556 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic062316z |
| 通讯作者 | Fu, hongbing(hongbing.fu@iccas.ac.cn) |
| 英文摘要 | The enantiomerically pure bis-bidentate ligands of bis(pyrrol-2-ylmethyleneamine)cyclohexane [h-2(l-r,l-s)] are easily synthesized from condensation of the pure r,r and s,s enantiomers of the 1,2-diaminecyclohexane spacer with 2 equiv of pyrrole-2-carbaldehyde. the coordination of [h-2(l-r,l-s)] with a h2o molecule and metal ions ni-ii, cu-ii, and zn-ii gives rise to distinct helical structures and crystal packing motifs: homochiral and enantiopure infinite single-helical polymeric chains of [(h-2(l-r,l-s)center dot h2o)(n)] via hydrogen bonds, mononuclear single helices of [ni-ii(l-r,l-s)] and [cu-ii(l-r,l-s)], and a double-stranded dinuclear helicate of [zn-2(ii)(l-r,l-s)(2)], respectively. the helical structures for all metal complexes in the solid state still remain in the solution. remarkably, chiral ligands of [h-2(l-r)] and [h-2(l-s)] predetermine the chirality of the helices and helicates, i.e., p left-handedness and m right-handedness, respectively. the structural changes of these complexes induced by different coordinators are also characterized by circular dichroism (cd) and absorption spectra in both the solid state and solution. analysis of cd spectra, with aids of absolute determination of single-crystal x-ray diffraction structures, reveals both intraligand and interligand chromophore couplings. for the potential applications of these complexes, other experiments such as magnetism, photoluminescence, and nonlinear optical properties have also been investigated. |
| WOS关键词 | TRIPLE-STRANDED HELICATE ; X-RAY-STRUCTURE ; DINUCLEAR COMPLEXES ; RATIONAL DESIGN ; CD SPECTRA ; STEREOSELECTIVE FORMATION ; 2ND-HARMONIC GENERATION ; MOLECULAR ARCHITECTURE ; DIPYRROMETHENE LIGANDS ; COORDINATION NETWORKS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000245871700018 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381233 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Fu, Hongbing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yaobing,Fu, Hongbing,Shen, Fugang,et al. Distinct m and p helical complexes of h2o and metal ions ni-ii, cu-ii, and zn-ii with enantiomerically pure chiral bis(pyrrol-2-ylmethyleneamine)cyclohexane ligands: crystal structures and circular dichroism properties[J]. Inorganic chemistry,2007,46(9):3548-3556. |
| APA | Wang, Yaobing.,Fu, Hongbing.,Shen, Fugang.,Sheng, Xiaohai.,Peng, Aidong.,...&Yao, Jiannian.(2007).Distinct m and p helical complexes of h2o and metal ions ni-ii, cu-ii, and zn-ii with enantiomerically pure chiral bis(pyrrol-2-ylmethyleneamine)cyclohexane ligands: crystal structures and circular dichroism properties.Inorganic chemistry,46(9),3548-3556. |
| MLA | Wang, Yaobing,et al."Distinct m and p helical complexes of h2o and metal ions ni-ii, cu-ii, and zn-ii with enantiomerically pure chiral bis(pyrrol-2-ylmethyleneamine)cyclohexane ligands: crystal structures and circular dichroism properties".Inorganic chemistry 46.9(2007):3548-3556. |
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来源：中国科学院大学
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