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Synthesis and characterization of poly(ethylene terephthalate)/attapulgite nanocomposites

文献类型:期刊论文

作者Yuan, Xuepei; Li, Chuncheng; Guan, Guohu; Liu, Xiaoqing; Mao, Yaonan; Zhang, Dong
刊名Journal of applied polymer science
出版日期2007-01-15
卷号103期号:2页码:1279-1286
关键词Poly(ethylene terephthalate) Polyesters Nanocomposites Clay Attapulgite
ISSN号0021-8995
DOI10.1002/app.25207
通讯作者Li, chuncheng(lizy@iccas.ac.cn)
英文摘要A kind of clay with fibrous morphology, attapulgite (at), was used to prepare poly (ethylene terephthalate) (pet)/at nanocomposites via in situ polymerization. attapulgite was modified with hexadecyltriphenylphosphonium bromide and silane coupling agent (3-glycidoxypropitrimethoxysilane) to increase the dispersion of clay particles in polymer matrix and the interaction between clay particles and polymer matrix. ftir and tga test of the organic-at particles investigated the thermal stability and the loading quantity of organic reagents. xrd patterns and sem micrographs showed that the organic modification was processed on the surface of rod-like crystals and did not shift the crystal structure of silicate. for pet/at nanocomposites, it was revealed in tem that the fibrous clay can be well dispersed in polymer matrix with the rod-like crystals in the range of nanometer scale. the diameter of rod-like crystal is about 20 nm and the length is near to 500 nm. the addition of the clay particles can enhance the thermal stability and crystallization rate of pet. with the addition of at in pet matrix, the flexural modulus of those composites was also increased markedly. (c) 2006 wiley periodicals, inc.
WOS关键词POLY(ETHYLENE-TEREPHTHALATE) NANOCOMPOSITES ; LAYERED SILICATE ; NA-ATTAPULGITE ; POLYMERIZATION ; FIBERS ; MORPHOLOGY ; CRYSTALLIZATION ; COMPOSITES ; DISPERSION ; HYBRID
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
WOS记录号WOS:000242468700081
出版者JOHN WILEY & SONS INC
URI标识http://www.irgrid.ac.cn/handle/1471x/2381251
专题中国科学院大学
通讯作者Li, Chuncheng
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, CAS Key Lab Engn Plast,Joint Lab Polymer Sci & Ma, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Yuan, Xuepei,Li, Chuncheng,Guan, Guohu,et al. Synthesis and characterization of poly(ethylene terephthalate)/attapulgite nanocomposites[J]. Journal of applied polymer science,2007,103(2):1279-1286.
APA Yuan, Xuepei,Li, Chuncheng,Guan, Guohu,Liu, Xiaoqing,Mao, Yaonan,&Zhang, Dong.(2007).Synthesis and characterization of poly(ethylene terephthalate)/attapulgite nanocomposites.Journal of applied polymer science,103(2),1279-1286.
MLA Yuan, Xuepei,et al."Synthesis and characterization of poly(ethylene terephthalate)/attapulgite nanocomposites".Journal of applied polymer science 103.2(2007):1279-1286.

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来源:中国科学院大学

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