Two novel anion-directed cu(ii) double betaine coordination polymers with different open frameworks: inorganic chains [cu-3([mu(3)-oh)(2)(mu(2)-h2o)(2)](n) as secondary building units with unusual chair-like [cu3o4] cores
文献类型：期刊论文
| 作者 | Li, Yan; Zou, Jian-Ping; Zou, Wen-Qiang; Zheng, Fa-Kun; Guo, Guo-Cong; Lu, Can-Zhong; Huang, Jin-Shun |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2007-09-01 |
| 卷号 | 10期号:9页码:1026-1030 |
| 关键词 | Anion template Coordination polymers Crystal structure Double betaine Inorganic chain |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2007.05.020 |
| 通讯作者 | Zheng, fa-kun(zfk@fjirsm.ac.cn) |
| 英文摘要 | The reaction of double betaine ligand l-1(l-1 = 1,3-bis(pyridinio-4-carboxylato)-propane) with cu(clo4)(2) and cu(no3)(2), respectively, afforded two novel anion-directed coordination polymers with different open frameworks. the structure of [cu3(l-1)(2)(oh)(2)(h2o)(2)](clo4)(4)center dot 2h(2)o 1 is a unique 3-d open-framework with large s-shape channels, while [cu3(l2(1))(2)(oh)(2)(h2o)(2)](no3)(4)-2h(2)o 2 has a 2-d tubular structure. there exist inorganic copper-oxo chains [cu3(l-1)(2)-(oh)(2)(h2o)(2)](n) in both 1 and 2 as secondary building units, in which the [cu3o4] cores exhibit a rarely observed chair-like configuration. the anion template of clo4- and no3-, and labile coordination orientation of l-1 ligand prompt the formation of different polymeric networks in 1 and 2. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | FLEXIBLE DOUBLE BETAINES ; DICARBOXYLATE-LIKE LIGANDS ; METAL-ORGANIC FRAMEWORKS ; STRUCTURAL DIVERSITY ; MAGNETIC-PROPERTIES ; COPPER(II) COMPLEX ; CRYSTAL-STRUCTURES ; NETWORK SOLIDS ; CHANNELS ; DESIGN |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000249460300015 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381311 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zheng, Fa-Kun |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yan,Zou, Jian-Ping,Zou, Wen-Qiang,et al. Two novel anion-directed cu(ii) double betaine coordination polymers with different open frameworks: inorganic chains [cu-3([mu(3)-oh)(2)(mu(2)-h2o)(2)](n) as secondary building units with unusual chair-like [cu3o4] cores[J]. Inorganic chemistry communications,2007,10(9):1026-1030. |
| APA | Li, Yan.,Zou, Jian-Ping.,Zou, Wen-Qiang.,Zheng, Fa-Kun.,Guo, Guo-Cong.,...&Huang, Jin-Shun.(2007).Two novel anion-directed cu(ii) double betaine coordination polymers with different open frameworks: inorganic chains [cu-3([mu(3)-oh)(2)(mu(2)-h2o)(2)](n) as secondary building units with unusual chair-like [cu3o4] cores.Inorganic chemistry communications,10(9),1026-1030. |
| MLA | Li, Yan,et al."Two novel anion-directed cu(ii) double betaine coordination polymers with different open frameworks: inorganic chains [cu-3([mu(3)-oh)(2)(mu(2)-h2o)(2)](n) as secondary building units with unusual chair-like [cu3o4] cores".Inorganic chemistry communications 10.9(2007):1026-1030. |
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来源：中国科学院大学
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