Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)
文献类型：期刊论文
| 作者 | Zhao, Jun-Wei; Zhang, Jie; Zheng, Shou-Tian; Yang, Guo-Yu |
| 刊名 | Inorganic chemistry
 |
| 出版日期 | 2007-12-24 |
| 卷号 | 46期号:26页码:10944-10946 |
| ISSN号 | 0020-1669 |
| 通讯作者 | Yang, guo-yu(ygy@fjirsm.ac.cn) |
| 英文摘要 | A novel tetrameric cluster, (en h-2)(3.5)h-15[{(fefeiii)-fe-ii](12)(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)]center dot 83h(2)o (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by ir, optical diffuse reflectance, thermogravimetric analysis, and single-crystal x-ray diffraction. the skeleton of 1 is composed of four tri-fe-iii-substituted [fe-3(iii)(mu(3)-oh)(3)(b-alpha-pw9o34)](3-) keggin moieties fused together through a (fe2o2)-o-ii unit and four mu(4)-po4 bridges, resulting in a unique tetramer with c-2 symmetry. magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between fe-ii and fe-iii centers. |
| WOS关键词 | MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURE ; COMPLEXES ; POLYOXOTUNGSTATE ; HETEROPOLYANIONS ; TUNGSTOPHOSPHATE ; POLYOXOANIONS ; COORDINATION ; ANIONS ; WHEEL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000251773700003 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381459 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, Guo-Yu |
| 作者单位 | Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Jun-Wei,Zhang, Jie,Zheng, Shou-Tian,et al. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)[J]. Inorganic chemistry,2007,46(26):10944-10946. |
| APA | Zhao, Jun-Wei,Zhang, Jie,Zheng, Shou-Tian,&Yang, Guo-Yu.(2007).Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-).Inorganic chemistry,46(26),10944-10946. |
| MLA | Zhao, Jun-Wei,et al."Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. a novel tetrameric cluster of [{(fefe12iii)-fe-ii(mu(3)-oh)(12)(mu(4)-po4)(4)}(b-alpha-pw9o34)(4)](22-)".Inorganic chemistry 46.26(2007):10944-10946. |
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来源：中国科学院大学
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