Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production
文献类型：期刊论文
| 作者 | Xiong, Zhitao1; Wu, Guotao3; Chua, Yong Shen2; Hu, Jianjiang1; He, Teng; Xu, Weiliang2; Chen, Ping1,2,3 |
| 刊名 | energy & environmental science
 |
| 出版日期 | 2008 |
| 卷号 | 1期号:3页码:360-363 |
| 产权排序 | 3;2 |
| 通讯作者 | 陈萍 |
| 英文摘要 | the prospect of building a future energy system on hydrogen has stimulated much research effort in developing hydrogen storage technologies. one of the potential materials newly developed is sodium amidoborane (nanh2bh3) which evolves similar to 7.5 wt% hydrogen at temperatures as low as 91 degrees c. in this paper, two methods of synthesizing pure nanh2bh3 were reported. one method is by reacting nah and ammonia borane in thf at low temperatures, and the other is by reacting nanh2 and ammonia borane in thf at ambient temperature. non-isothermal testing on the thermolysis of solid nanh2bh3 showed that hydrogen evolution was composed of two exothermic steps. more than 1 equiv. h-2 was evolved rapidly at temperatures below 87 degrees c. after evolving 2 equiv. h-2, nah was identified in solid products and coexisted with amorphous bn. |
| WOS标题词 | science & technology ; physical sciences ; technology ; life sciences & biomedicine |
| 类目[WOS] | chemistry, multidisciplinary ; energy & fuels ; engineering, chemical ; environmental sciences |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering ; environmental sciences & ecology |
| 关键词[WOS] | ammonia-borane ; thermal-decomposition ; storage ; imides |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000263887900013 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101801]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore 2.Natl Univ Singapore, Dept Chem, Singapore 117542, Singapore 3.Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Zhitao,Wu, Guotao,Chua, Yong Shen,et al. Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production[J]. energy & environmental science,2008,1(3):360-363. |
| APA | Xiong, Zhitao.,Wu, Guotao.,Chua, Yong Shen.,Hu, Jianjiang.,He, Teng.,...&Chen, Ping.(2008).Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production.energy & environmental science,1(3),360-363. |
| MLA | Xiong, Zhitao,et al."Synthesis of sodium amidoborane (NaNH2BH3) for hydrogen production".energy & environmental science 1.3(2008):360-363. |
入库方式： OAI收割
来源：大连化学物理研究所
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