Effect of in situ synthesized macroactivator on morphology of pa6/ps blends via successive polymerization
文献类型：期刊论文
| 作者 | Pei, Aihua; Liu, Andong; Xie, Tingxiu; Yang, Guisheng |
| 刊名 | Journal of applied polymer science
 |
| 出版日期 | 2007-08-15 |
| 卷号 | 105期号:4页码:1757-1765 |
| ISSN号 | 0021-8995 |
| 关键词 | Macroactivator Tmi Ps-g-pa6 Ps/pa6 blends Morphology |
| DOI | 10.1002/app.25650 |
| 通讯作者 | Yang, guisheng(ygs@geniuscn.com) |
| 英文摘要 | In situ polymerization and in situ compatibilization was adopted for preparation of ternary pa6/ps-g-pa6/ps blends by means of successive polymerization of styrene, with tmi and epsilon-caprolactam, via free radical copolymerization and anionic ring-opening polymerization, respectively. copolymer poly(st-g-tmi), the chain of which bears isocyanate (-nco), acts as a macroactivator to initiate pa6 chain growth from the ps chain and graft copolymer of ps-g-pa6 and pure pa6 form, simultaneously. the effect of the macroactivator poly(st-g-tmi) on the phase morphology was investigated in detail, using scanning electron microscopy. in case of blends with higher content of ps-g-pa6 copolymer, copolymer nanoparticles coexisting with the ps formed the matrix, in which pa6 microspheres were dispersed evenly as minor phase. the content of the compositions (homopolystyrene, homopolyamide 6, and ps-g-pa6) of the blends were determined by selective solvent extraction technique. the mechanical properties of pa6/ps-g-pa6/ps blends were better than that of pa6/ps blends. especially for the blends t10 with lower ps-g-pa6 copolymer content, both the flexural strength and flexural modulus showed significantly improving because of the improved interfacial adhesion between ps and pa6. (c) 2007 wiley periodicals, inc. |
| WOS关键词 | FREE-RADICAL COPOLYMERIZATION ; REACTIVE EXTRUSION ; PHASE MORPHOLOGY ; POLYAMIDE 6 ; PART 1 ; STYRENE ; ISOCYANATE ; COMPATIBILIZATION |
| WOS研究方向 | Polymer Science |
| WOS类目 | Polymer Science |
| 语种 | 英语 |
| 出版者 | JOHN WILEY & SONS INC |
| WOS记录号 | WOS:000247576600006 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381693 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Yang, Guisheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Technol, Key Lab Engn Plast,Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pei, Aihua,Liu, Andong,Xie, Tingxiu,et al. Effect of in situ synthesized macroactivator on morphology of pa6/ps blends via successive polymerization[J]. Journal of applied polymer science,2007,105(4):1757-1765. |
| APA | Pei, Aihua,Liu, Andong,Xie, Tingxiu,&Yang, Guisheng.(2007).Effect of in situ synthesized macroactivator on morphology of pa6/ps blends via successive polymerization.Journal of applied polymer science,105(4),1757-1765. |
| MLA | Pei, Aihua,et al."Effect of in situ synthesized macroactivator on morphology of pa6/ps blends via successive polymerization".Journal of applied polymer science 105.4(2007):1757-1765. |
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来源：中国科学院大学
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