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Chemical and physical properties of copper and nitrogen plasma-implanted polyethylene

文献类型:期刊论文

作者Zhang, Wei; Ji, Junhui; Zhang, Yihe; Yan, Qing; Chu, Paul K.
刊名Plasma processes and polymers
出版日期2007-02-22
卷号4期号:2页码:158-164
关键词Copper Plasma immersion ion implantation Polyethylene Xps
ISSN号1612-8850
DOI10.1002/ppap.200600196
通讯作者Chu, paul k.(paul.chu@cityu.edu.hk)
英文摘要Plasma immersion ion implantation (piii) is a new technique used to modify the surface physical and chemical properties of polymers for antibacterial purposes. our previous research work has shown that copper and nitrogen piii can give rise to excellent antibacterial properties on polyethylene (pe) substrates. in this paper, the effects of the piii conditions on the chemical and physical properties of the cu and n plasma-implanted pe are investigated. elemental depth profiles show that cu and n piii results in the formation of c-n, c=n bonds in the surface region, and that the implanted cu does not bond with the polymer matrix elements. a longer piii time increases the concentrations of c=n, c=n and c-n bonds formed in the near-surface region, but the elemental chemical states deeper into the sample remain about the same for different piii time durations. however, if n-piii and cu-piii are not carried out simultaneously, for example, n-piii following cu-piii, the retained cu dose is affected due to nitrogen sputtering, but the cu chemical state is not altered. in addition, more c=n and c=n bonds are formed in the outer surface region. a longer n-piii implantation time further enriches these chemical functional groups.
WOS关键词IMMERSION ION-IMPLANTATION ; SURFACE MODIFICATION ; BIOMEDICAL APPLICATIONS ; POLYMERS ; IMPROVEMENT ; ADHESION ; FILMS
WOS研究方向Physics ; Polymer Science
WOS类目Physics, Applied ; Physics, Fluids & Plasmas ; Physics, Condensed Matter ; Polymer Science
语种英语
WOS记录号WOS:000244807300005
出版者WILEY-V C H VERLAG GMBH
URI标识http://www.irgrid.ac.cn/handle/1471x/2381845
专题中国科学院大学
通讯作者Chu, Paul K.
作者单位1.City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
2.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
4.China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China
5.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Wei,Ji, Junhui,Zhang, Yihe,et al. Chemical and physical properties of copper and nitrogen plasma-implanted polyethylene[J]. Plasma processes and polymers,2007,4(2):158-164.
APA Zhang, Wei,Ji, Junhui,Zhang, Yihe,Yan, Qing,&Chu, Paul K..(2007).Chemical and physical properties of copper and nitrogen plasma-implanted polyethylene.Plasma processes and polymers,4(2),158-164.
MLA Zhang, Wei,et al."Chemical and physical properties of copper and nitrogen plasma-implanted polyethylene".Plasma processes and polymers 4.2(2007):158-164.

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来源:中国科学院大学

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