Low temperature heat capacities and standard molar enthalpy of formation of sodium benzoate C6H5COONa (s)
文献类型：期刊论文
| 作者 | Kong, Yu-Xia1; Di, You-Ying1; Qi, Yu-Dong1; Yang, Wei-Wei1; Tan, Zhi-Cheng2 |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2009-05-05 |
| 卷号 | 488期号:1-2页码:27-32 |
| 关键词 | Sodium benzoate Adiabatic calorimeter Heat capacity Thermodynamic function Isoperibol solution-reaction calorimeter Standard molar enthalpy of formation |
| 产权排序 | 5;2 |
| 通讯作者 | you-ying di |
| 英文摘要 | sodium benzoate was synthesized by the method of liquid phase synthesis, in which benzoic acid and anhydrous sodium carbonate were chosen as the reactants. the structure and composition of the compound were characterized by ftir, chemical analysis, elemental analysis and x-ray powder diffraction techniques. low temperature heat capacities of the compound were measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 k. a polynomial equation of the heat capacities as a function of the temperature was fitted by least square method. the smoothed heat capacities and the thermodynamic functions of the compound relative to 298.15 k have been calculated based on the equation. in accordance with hess law, the standard molar enthalpy of formation of the title compound c6h5coona (s) was determined to be delta h-gamma(m)sigma[c6h5coona.s] = -(642.56 +/- 0.64) kj mol(-1) by using an isoperibol solution-reaction calorimeter. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000265477400005 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101881]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong, Yu-Xia,Di, You-Ying,Qi, Yu-Dong,et al. Low temperature heat capacities and standard molar enthalpy of formation of sodium benzoate C6H5COONa (s)[J]. thermochimica acta,2009,488(1-2):27-32. |
| APA | Kong, Yu-Xia,Di, You-Ying,Qi, Yu-Dong,Yang, Wei-Wei,&Tan, Zhi-Cheng.(2009).Low temperature heat capacities and standard molar enthalpy of formation of sodium benzoate C6H5COONa (s).thermochimica acta,488(1-2),27-32. |
| MLA | Kong, Yu-Xia,et al."Low temperature heat capacities and standard molar enthalpy of formation of sodium benzoate C6H5COONa (s)".thermochimica acta 488.1-2(2009):27-32. |
入库方式： OAI收割
来源：大连化学物理研究所
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