Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(ii) enrichment of its co-reactants
文献类型：期刊论文
| 作者 | Xu, Yuanhong; Gao, Ying; Li, Tao; Du, Yan; Li, Jing; Wang, Erkang |
| 刊名 | Advanced functional materials
 |
| 出版日期 | 2007-04-16 |
| 卷号 | 17期号:6页码:1003-1009 |
| ISSN号 | 1616-301X |
| DOI | 10.1002/adfm.200600537 |
| 通讯作者 | Wang, erkang(ekwang@ciac.jl.cn) |
| 英文摘要 | An enhanced electrochemiluminescence (ecl) efficiency is obtained from the ruthenium complex tris(2,2'-bipyridyl)ruthenium(ii) (ru(bpy)(3)(2+)) by introduction of an ionic liquid (il) 1-butyl-3-methylimidazolium tetrafluoroborate (bmimbf(4)). upon addition of 1% (v/v) bmimbf(4) to 0.1 mm ru(bpy)(3)(2+) solution, a maximum increase in ecl intensity is obtained both at an indium tin oxide (ito) electrode (15-fold) and at a glassy carbon (gc) electrode (5- to 64old). furthermore, upon addition of 1% (v/v) bmimbf4 to 5 pm ru(bpy)(3)(2+)/100 mm co-reactant systems at a gc electrode, il adsorption occurs at the electrode surface, which results in a change of the polarity of the electrode surface. such functionalization greatly improves the functions of both ru(bpy)(3)(2+) and ionic liquids, as is demonstrated in the sensitive and selective concentration enrichment of the ru(bpy)(3)(2+) co-reactants. |
| WOS关键词 | TEMPERATURE IONIC LIQUIDS ; ELECTROGENERATED CHEMILUMINESCENCE ; ELECTROCHEMICAL APPLICATIONS ; PHYSICAL-PROPERTIES ; EMISSION INTENSITY ; CHEMICAL-ANALYSIS ; ORGANIC-SOLVENTS ; GREEN SOLVENTS ; LIGHT-EMISSION ; MOLTEN-SALTS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000246414100020 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381944 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wang, Erkang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Grad Sch, Changchun 130022, Jilin, Peoples R China 2.Changchun Inst Technol, Dept Appl Chem, Changchun 130021, Jilin, Peoples R China 3.Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Yuanhong,Gao, Ying,Li, Tao,et al. Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(ii) enrichment of its co-reactants[J]. Advanced functional materials,2007,17(6):1003-1009. |
| APA | Xu, Yuanhong,Gao, Ying,Li, Tao,Du, Yan,Li, Jing,&Wang, Erkang.(2007).Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(ii) enrichment of its co-reactants.Advanced functional materials,17(6),1003-1009. |
| MLA | Xu, Yuanhong,et al."Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(ii) enrichment of its co-reactants".Advanced functional materials 17.6(2007):1003-1009. |
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来源：中国科学院大学
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