(n-cnh2n-1)-1,3-azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of [fefe]-hydrogenases: the influence of the bridge on the diiron complex
文献类型：期刊论文
| 作者 | Si, Youtao; Ma, Chengbing; Hu, Mingqiang; Chen, Hui; Chen, Changneng; Liu, Qiutian |
| 刊名 | New journal of chemistry
 |
| 出版日期 | 2007 |
| 卷号 | 31期号:8页码:1448-1454 |
| ISSN号 | 1144-0546 |
| DOI | 10.1039/b616236c |
| 通讯作者 | Chen, changneng(ccn@fjirsm.ac.cn) |
| 英文摘要 | To further understand the e. ects of 1,3- azadithiolate (adt) bridges on the structures and properties of diiron complexes, a novel family of (n- cnh2n - 1)- 1,3- azapropanedithiolate- bridged diiron complexes [fe-2( co) (6)( ch2s) n-2 - cnh(2n) - 1] (n = 5, 6, 7) and their pme3- disubstituted complexes [fe-2(co) (4)( pme3) (2)( ch2s) n-2 - cnh(2)n - 1] (n = 5, 6, 7) were synthesized as mimics of [ fefe]- hydrogenases. our studies suggest that the coordination con. gurations, co stretching frequencies, (1) h and (31) p nmr signals, redox potentials and electrocatalytic h-2- production processes of diiron complexes are closely pertinent to the electron- donating abilities and steric chemistry of the adt bridges. |
| WOS关键词 | FE-ONLY HYDROGENASES ; IRON HYDROGENASE ; CRYSTAL-STRUCTURE ; MODEL ; CHEMISTRY ; COORDINATION ; EVOLUTION ; CLUSTER |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000248354300019 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381949 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Chen, Changneng |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China 2.Grad Univ Chinese Acad Sci, Dept Chem, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Si, Youtao,Ma, Chengbing,Hu, Mingqiang,et al. (n-cnh2n-1)-1,3-azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of [fefe]-hydrogenases: the influence of the bridge on the diiron complex[J]. New journal of chemistry,2007,31(8):1448-1454. |
| APA | Si, Youtao,Ma, Chengbing,Hu, Mingqiang,Chen, Hui,Chen, Changneng,&Liu, Qiutian.(2007).(n-cnh2n-1)-1,3-azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of [fefe]-hydrogenases: the influence of the bridge on the diiron complex.New journal of chemistry,31(8),1448-1454. |
| MLA | Si, Youtao,et al."(n-cnh2n-1)-1,3-azapropanedithiolate (n=5, 6, 7)-bridged diiron complexes as mimics for the active site of [fefe]-hydrogenases: the influence of the bridge on the diiron complex".New journal of chemistry 31.8(2007):1448-1454. |
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