Hydrothermal synthesis and characterization of a new 1-d polymeric lanthanum ethylenediaminetetraacetate with less metal-aqua coordination: {[la(edta)(h2o)](2)}(n)
文献类型：期刊论文
| 作者 | Xiong, Ding-Bang; Chen, Hao-Hong; Yang, Xin-Xin; Zhao, Jing-Tai |
| 刊名 | Inorganica chimica acta
 |
| 出版日期 | 2007-04-01 |
| 卷号 | 360期号:5页码:1616-1620 |
| 关键词 | Hydrothermal synthesis Crystal structure Coordination polymer Lanthanum Edta |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2006.08.044 |
| 通讯作者 | Zhao, jing-tai(jtzhao@mail.sic.ac.cn) |
| 英文摘要 | A new lanthanum ethylenediaminetetraacetate (edta) coordination polymer, {[la(edta)(h2o)](2)}(n) (edta(3-) = [(ch2n)(2)(ch2-cooh)(ch2coo-)(3)]), was hydrothermally prepared from lacl3 solution and ethylenediaminetetracetic acid at 448 k. the compound was characterized by elemental analysis, ftir, tg-dta, and x-ray crystallography. the structure consists of ladder-like chains of [la(edta)(h2o)](2) dimers bridged by o-c-o groups. hydrothermal method successfully reduced the high number of la-aqua coordinations in known lanthanum edta to one giving rise to relatively compact structure. it has high thermal stability up to 550 k. every edta ligand with cooh group is involved in eight la o(n) bonds to three nine-coordinated la centers. (c) 2006 elsevier b.v. all rights reserved. |
| WOS关键词 | CRYSTAL-STRUCTURE ; FRAMEWORK ; BEHAVIOR ; DESIGN ; CONTRACTION ; CLUSTER ; STORAGE ; ANIONS ; SALTS ; UNITS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000245772300025 |
| 出版者 | ELSEVIER SCIENCE SA |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2381999 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Zhao, Jing-Tai |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Ding-Bang,Chen, Hao-Hong,Yang, Xin-Xin,et al. Hydrothermal synthesis and characterization of a new 1-d polymeric lanthanum ethylenediaminetetraacetate with less metal-aqua coordination: {[la(edta)(h2o)](2)}(n)[J]. Inorganica chimica acta,2007,360(5):1616-1620. |
| APA | Xiong, Ding-Bang,Chen, Hao-Hong,Yang, Xin-Xin,&Zhao, Jing-Tai.(2007).Hydrothermal synthesis and characterization of a new 1-d polymeric lanthanum ethylenediaminetetraacetate with less metal-aqua coordination: {[la(edta)(h2o)](2)}(n).Inorganica chimica acta,360(5),1616-1620. |
| MLA | Xiong, Ding-Bang,et al."Hydrothermal synthesis and characterization of a new 1-d polymeric lanthanum ethylenediaminetetraacetate with less metal-aqua coordination: {[la(edta)(h2o)](2)}(n)".Inorganica chimica acta 360.5(2007):1616-1620. |
入库方式： iSwitch采集
来源：中国科学院大学
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。