A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: synthesis, crystal structure and properties of (hapy)(4)[co(h2o)(5)mo7o24]center dot 9h(2)o
文献类型：期刊论文
| 作者 | Li, Taohai; Lue, Han; Gao, Shuiying; Cao, Rong |
| 刊名 | Inorganic chemistry communications
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 10期号:11页码:1342-1346 |
| 关键词 | Supported polyoxometalate Heptamolybdate anions Supramolecular Magnetic property Electrochemical property |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2007.07.018 |
| 通讯作者 | Cao, rong(rcao@fjirsm.ac.cn) |
| 英文摘要 | A new supramolecular compound based on the heptamolybdate anion, formulated as (hapy)(4)[co(h2o)(5)mo7o24]center dot 9h(2)o (1) (apy = 2-aminopyridine), has been synthesized hydrothermally and characterized by elemental analyses, ir, and x-ray single crystal diffraction. compound 1 crystallizes as alternating layers of inorganic anions and organic cations linked by hydrogen-bonding interactions. a variable-temperature magnetic susceptibility measurement of 1 demonstrated the presence of antiferromagnetic interactions. furthermore, the cyclic voltammograin of i shows two reversible redox couples both of which are associated with two-electron processes of molybdenum. (c) 2007 elsevier b.v. all rights reserved. |
| WOS关键词 | HYDROTHERMAL SYNTHESIS ; COORDINATION POLYMERS ; COMPOSITE-SOLIDS ; HYDROGEN-BOND ; CLUSTERS ; POLYOXOMETALATE ; COMPLEXES ; OCTAMOLYBDATE ; CATALYSIS ; LIGANDS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000251522700027 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2382018 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Cao, Rong |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Taohai,Lue, Han,Gao, Shuiying,et al. A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: synthesis, crystal structure and properties of (hapy)(4)[co(h2o)(5)mo7o24]center dot 9h(2)o[J]. Inorganic chemistry communications,2007,10(11):1342-1346. |
| APA | Li, Taohai,Lue, Han,Gao, Shuiying,&Cao, Rong.(2007).A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: synthesis, crystal structure and properties of (hapy)(4)[co(h2o)(5)mo7o24]center dot 9h(2)o.Inorganic chemistry communications,10(11),1342-1346. |
| MLA | Li, Taohai,et al."A new heptamolybdate-based supramolecular compound with an alternating organic and inorganic layer structure: synthesis, crystal structure and properties of (hapy)(4)[co(h2o)(5)mo7o24]center dot 9h(2)o".Inorganic chemistry communications 10.11(2007):1342-1346. |
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来源：中国科学院大学
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