Co2 reforming of ch4 over mesoporous ni/cao-zro2 nanocomposite
文献类型:期刊论文
作者 | Liu Shuigang1,2; Li Junping1; Zhao Ning1; Wei Wei1; Sun Yuhan1 |
刊名 | Chinese journal of catalysis
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出版日期 | 2007-11-01 |
卷号 | 28期号:11页码:1019-1023 |
关键词 | Nickel Calcium oxide Zirconia Nanocomposite Supported catalyst Methane Carbon dioxide Reforming |
ISSN号 | 0253-9837 |
通讯作者 | Sun yuhan(yhsun@sxicc.ac.cn) |
英文摘要 | A novel mesoporous ni/cao-zro2 nanocomposite was prepared by a the sol-gel method. the nanocomposite was used for co2 reforming of ch4, and it exhibited high catalytic activity, thermal stability, and resistance to coking. after running in the fixed-bed reactor for 50 h, its catalytic activity hardly decreased, and only a small amount of carbon formed on the catalyst, meaning that the catalyst stability was better than ni/al2o3 or ni/sio2 catalyst. the nickel particles almost kept their original nanometer size during the reaction owing to that the size growth was inhibited by other components in the nanocomposite. in addition, cao was favorable for the chermsorption of co2 in the reaction and consequently improved the resistance to carbon deposition on the mesoporous ni/cao-zro2 nanocomposite. |
WOS关键词 | CATALYSTS ; METHANE ; SYNGAS ; NICKEL |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
语种 | 英语 |
WOS记录号 | WOS:000251594300018 |
出版者 | SCIENCE CHINA PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2382033 |
专题 | 中国科学院大学 |
通讯作者 | Sun Yuhan |
作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Grad Univ Beijing, Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu Shuigang,Li Junping,Zhao Ning,et al. Co2 reforming of ch4 over mesoporous ni/cao-zro2 nanocomposite[J]. Chinese journal of catalysis,2007,28(11):1019-1023. |
APA | Liu Shuigang,Li Junping,Zhao Ning,Wei Wei,&Sun Yuhan.(2007).Co2 reforming of ch4 over mesoporous ni/cao-zro2 nanocomposite.Chinese journal of catalysis,28(11),1019-1023. |
MLA | Liu Shuigang,et al."Co2 reforming of ch4 over mesoporous ni/cao-zro2 nanocomposite".Chinese journal of catalysis 28.11(2007):1019-1023. |
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来源:中国科学院大学
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