An efficient route for the construction of cyclopenta[b]quinoline derivatives via intramolecular cyclopropanation
文献类型：期刊论文
| 作者 | Huang, Haoxi1,2,3; Hu, Wenhao1 |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2007-11-26 |
| 卷号 | 63期号:48页码:11850-11855 |
| 关键词 | Cyclopenta[b]quinoline Cyclopropanation Dirhodium(ii) Diazo compounds Carbene |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2007.09.034 |
| 通讯作者 | Hu, wenhao(whu@chem.ecnu.edu.cn) |
| 英文摘要 | A one-pot process to introduce diazoacetoacetate functionality into quinoline was identified with excellent yield and regioselectivity. an intramolecular cyclopropanation of the resulting adducts gave tetracyclic cyclopenta[b]quinoline derivatives in nearly quantitative yields. a synthetic utility of the tetracyclic derivatives was examined by a simple ring opening reaction to afford cyclopenta[ b] quinoline in a good yield. (c) 2007 elsevier ltd. all rights reserved. |
| WOS关键词 | ALLYLIC TIN REAGENTS ; SILYL ENOL ETHERS ; NUCLEOPHILIC-ADDITION ; ASYMMETRIC-SYNTHESIS ; RADICAL ANNULATIONS ; CARBONYL-COMPOUNDS ; REACTION SEQUENCE ; FUSED QUINOLINES ; CATALYTIC AMOUNT ; FACILE ADDITION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000252094500008 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2382064 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Hu, Wenhao |
| 作者单位 | 1.E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China 2.Chinese Acad Sci, Inst Organ Chem, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Haoxi,Hu, Wenhao. An efficient route for the construction of cyclopenta[b]quinoline derivatives via intramolecular cyclopropanation[J]. Tetrahedron,2007,63(48):11850-11855. |
| APA | Huang, Haoxi,&Hu, Wenhao.(2007).An efficient route for the construction of cyclopenta[b]quinoline derivatives via intramolecular cyclopropanation.Tetrahedron,63(48),11850-11855. |
| MLA | Huang, Haoxi,et al."An efficient route for the construction of cyclopenta[b]quinoline derivatives via intramolecular cyclopropanation".Tetrahedron 63.48(2007):11850-11855. |
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来源：中国科学院大学
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