An efficient solid acid catalyst: Poly-p-styrenesulfonic acid supported on SBA-15 via surface-initiated ATRP
文献类型：期刊论文
| 作者 | Li, Congming; Yang, Jie; Wang, Peiyuan; Liu, Jian; Yang, Qihua |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2009-07-01 |
| 卷号 | 123期号:1-3页码:228-233 |
| 关键词 | SBA-15 Organic-inorganic hybrid materials Poly-p-styrenesulfonic acid Atom transfer radical polymerization (ATRP) |
| 产权排序 | 1;1 |
| 通讯作者 | 杨启华 |
| 英文摘要 | the sulfonic acid-functionalized mesoporous organic-inorganic hybrid materials were synthesized via atom transfer radical polymerization (atrp) method. sba-15 material was first grafted with 4-(chloromethyl)phenyltrimethoxysilane. the surface-initiated polymerization of sodium p-styrenesulfonate inside the pore wall of functionalized sba-15 results in p-styrenesulfonic acid functionalized sba-15 (pss-sba-15). the results of ft-ir, nitrogen sorption isotherm, xrd, tem and thermal gravimetric analyses (tga) confirm that the pss-sba-15 materials have ordered mesoporous structure, open channels and styrenesulfonic acid functionalities. the catalytic activity of pss-sba-15 was higher than commercial nafion resin in the esterification of lauric acid with ethanol. the unique catalytic performance of pss-sba-15 is probably attributed to the increased accessibility of the active sites to the reactants because of the existence of styrenesulfonic acid on the pore surface of sba-15. (c) 2009 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | transfer radical polymerization ; mesoporous organosilicas ; silica ; nanoparticles ; particles ; copolymer ; triblock |
| 收录类别 | SCI |
| 原文出处 | false |
| 语种 | 英语 |
| WOS记录号 | WOS:000267099000028 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/101927]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Congming,Yang, Jie,Wang, Peiyuan,et al. An efficient solid acid catalyst: Poly-p-styrenesulfonic acid supported on SBA-15 via surface-initiated ATRP[J]. microporous and mesoporous materials,2009,123(1-3):228-233. |
| APA | Li, Congming,Yang, Jie,Wang, Peiyuan,Liu, Jian,&Yang, Qihua.(2009).An efficient solid acid catalyst: Poly-p-styrenesulfonic acid supported on SBA-15 via surface-initiated ATRP.microporous and mesoporous materials,123(1-3),228-233. |
| MLA | Li, Congming,et al."An efficient solid acid catalyst: Poly-p-styrenesulfonic acid supported on SBA-15 via surface-initiated ATRP".microporous and mesoporous materials 123.1-3(2009):228-233. |
入库方式： OAI收割
来源：大连化学物理研究所
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